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Poly[μ-aqua-μ-(N,4-di­chloro-2-methyl­benzene­sulfonamidato)-potassium]

In the title compound, [K(C(7)H(6)Cl(2)NO(2)S)(H(2)O)](n), the K(+) cation is hepta­coordinated by two water O atoms, a sulfonyl O atom from each of four different N,4-dichloro-2-methyl­benzene­sulfonamidate anions and a Cl atom of one of the anions. Further, K—O—K bridges form extensive polymeric c...

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Detalles Bibliográficos
Autores principales: Spandana, H. S., Foro, Sabine, Gowda, B. Thimme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793672/
https://www.ncbi.nlm.nih.gov/pubmed/24109259
http://dx.doi.org/10.1107/S1600536813015845
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author Spandana, H. S.
Foro, Sabine
Gowda, B. Thimme
author_facet Spandana, H. S.
Foro, Sabine
Gowda, B. Thimme
author_sort Spandana, H. S.
collection PubMed
description In the title compound, [K(C(7)H(6)Cl(2)NO(2)S)(H(2)O)](n), the K(+) cation is hepta­coordinated by two water O atoms, a sulfonyl O atom from each of four different N,4-dichloro-2-methyl­benzene­sulfonamidate anions and a Cl atom of one of the anions. Further, K—O—K bridges form extensive polymeric chains along the b axis. In the crystal structure, the anions are linked into layers parallel to (100) by O—H⋯Cl and O—H⋯N hydrogen bonds.
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spelling pubmed-37936722013-10-09 Poly[μ-aqua-μ-(N,4-di­chloro-2-methyl­benzene­sulfonamidato)-potassium] Spandana, H. S. Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [K(C(7)H(6)Cl(2)NO(2)S)(H(2)O)](n), the K(+) cation is hepta­coordinated by two water O atoms, a sulfonyl O atom from each of four different N,4-dichloro-2-methyl­benzene­sulfonamidate anions and a Cl atom of one of the anions. Further, K—O—K bridges form extensive polymeric chains along the b axis. In the crystal structure, the anions are linked into layers parallel to (100) by O—H⋯Cl and O—H⋯N hydrogen bonds. International Union of Crystallography 2013-07-03 /pmc/articles/PMC3793672/ /pubmed/24109259 http://dx.doi.org/10.1107/S1600536813015845 Text en © Spandana et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Spandana, H. S.
Foro, Sabine
Gowda, B. Thimme
Poly[μ-aqua-μ-(N,4-di­chloro-2-methyl­benzene­sulfonamidato)-potassium]
title Poly[μ-aqua-μ-(N,4-di­chloro-2-methyl­benzene­sulfonamidato)-potassium]
title_full Poly[μ-aqua-μ-(N,4-di­chloro-2-methyl­benzene­sulfonamidato)-potassium]
title_fullStr Poly[μ-aqua-μ-(N,4-di­chloro-2-methyl­benzene­sulfonamidato)-potassium]
title_full_unstemmed Poly[μ-aqua-μ-(N,4-di­chloro-2-methyl­benzene­sulfonamidato)-potassium]
title_short Poly[μ-aqua-μ-(N,4-di­chloro-2-methyl­benzene­sulfonamidato)-potassium]
title_sort poly[μ-aqua-μ-(n,4-di­chloro-2-methyl­benzene­sulfonamidato)-potassium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793672/
https://www.ncbi.nlm.nih.gov/pubmed/24109259
http://dx.doi.org/10.1107/S1600536813015845
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