Cargando…
Poly[μ-aqua-μ-(N,4-dichloro-2-methylbenzenesulfonamidato)-potassium]
In the title compound, [K(C(7)H(6)Cl(2)NO(2)S)(H(2)O)](n), the K(+) cation is heptacoordinated by two water O atoms, a sulfonyl O atom from each of four different N,4-dichloro-2-methylbenzenesulfonamidate anions and a Cl atom of one of the anions. Further, K—O—K bridges form extensive polymeric c...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793672/ https://www.ncbi.nlm.nih.gov/pubmed/24109259 http://dx.doi.org/10.1107/S1600536813015845 |
_version_ | 1782287088161390592 |
---|---|
author | Spandana, H. S. Foro, Sabine Gowda, B. Thimme |
author_facet | Spandana, H. S. Foro, Sabine Gowda, B. Thimme |
author_sort | Spandana, H. S. |
collection | PubMed |
description | In the title compound, [K(C(7)H(6)Cl(2)NO(2)S)(H(2)O)](n), the K(+) cation is heptacoordinated by two water O atoms, a sulfonyl O atom from each of four different N,4-dichloro-2-methylbenzenesulfonamidate anions and a Cl atom of one of the anions. Further, K—O—K bridges form extensive polymeric chains along the b axis. In the crystal structure, the anions are linked into layers parallel to (100) by O—H⋯Cl and O—H⋯N hydrogen bonds. |
format | Online Article Text |
id | pubmed-3793672 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37936722013-10-09 Poly[μ-aqua-μ-(N,4-dichloro-2-methylbenzenesulfonamidato)-potassium] Spandana, H. S. Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [K(C(7)H(6)Cl(2)NO(2)S)(H(2)O)](n), the K(+) cation is heptacoordinated by two water O atoms, a sulfonyl O atom from each of four different N,4-dichloro-2-methylbenzenesulfonamidate anions and a Cl atom of one of the anions. Further, K—O—K bridges form extensive polymeric chains along the b axis. In the crystal structure, the anions are linked into layers parallel to (100) by O—H⋯Cl and O—H⋯N hydrogen bonds. International Union of Crystallography 2013-07-03 /pmc/articles/PMC3793672/ /pubmed/24109259 http://dx.doi.org/10.1107/S1600536813015845 Text en © Spandana et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Spandana, H. S. Foro, Sabine Gowda, B. Thimme Poly[μ-aqua-μ-(N,4-dichloro-2-methylbenzenesulfonamidato)-potassium] |
title | Poly[μ-aqua-μ-(N,4-dichloro-2-methylbenzenesulfonamidato)-potassium] |
title_full | Poly[μ-aqua-μ-(N,4-dichloro-2-methylbenzenesulfonamidato)-potassium] |
title_fullStr | Poly[μ-aqua-μ-(N,4-dichloro-2-methylbenzenesulfonamidato)-potassium] |
title_full_unstemmed | Poly[μ-aqua-μ-(N,4-dichloro-2-methylbenzenesulfonamidato)-potassium] |
title_short | Poly[μ-aqua-μ-(N,4-dichloro-2-methylbenzenesulfonamidato)-potassium] |
title_sort | poly[μ-aqua-μ-(n,4-dichloro-2-methylbenzenesulfonamidato)-potassium] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793672/ https://www.ncbi.nlm.nih.gov/pubmed/24109259 http://dx.doi.org/10.1107/S1600536813015845 |
work_keys_str_mv | AT spandanahs polymaquamn4dichloro2methylbenzenesulfonamidatopotassium AT forosabine polymaquamn4dichloro2methylbenzenesulfonamidatopotassium AT gowdabthimme polymaquamn4dichloro2methylbenzenesulfonamidatopotassium |