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catena-Poly[[tri­phenyl­tin(IV)]-μ-N-(4-acetyl­phen­yl)maleamato]

The crystal structure of the polymeric title compound, [Sn(C(6)H(5))(3)(C(12)H(10)NO(4))](n), comprises polymeric chains whereby adjacent Sn atoms are bridged by carboxyl­ate and amide carbonyl O atoms [Sn—O = 2.115 (15) and 2.653 (1) Å, respectively]. The Sn(IV) atom is five-coordinated showing a d...

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Detalles Bibliográficos
Autores principales: Bhatti, Moazzam H., Yunus, Uzma, Mussarat, Nosheen, Helliwell, Madeleine, Prendergast, Richard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793673/
https://www.ncbi.nlm.nih.gov/pubmed/24109260
http://dx.doi.org/10.1107/S1600536813017613
Descripción
Sumario:The crystal structure of the polymeric title compound, [Sn(C(6)H(5))(3)(C(12)H(10)NO(4))](n), comprises polymeric chains whereby adjacent Sn atoms are bridged by carboxyl­ate and amide carbonyl O atoms [Sn—O = 2.115 (15) and 2.653 (1) Å, respectively]. The Sn(IV) atom is five-coordinated showing a distorted trigonal–bipyramid geometry, with the three phenyl ipso-C atoms defining the trigonal plane and the axial positions occupied by O atoms [O—Sn—O = 171.91 (5)°]. Intra­molecular N—H⋯O hydrogen bonding leads to a seven-membered loop. There is an intra­molecular C—H⋯O inter­action within the polymeric chain. An inter­molecular C—H⋯O inter­action along c links the polymeric chains into sheets which are linked into a three-dimensional network via C—H⋯π inter­actions.