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catena-Poly[[triphenyltin(IV)]-μ-N-(4-acetylphenyl)maleamato]
The crystal structure of the polymeric title compound, [Sn(C(6)H(5))(3)(C(12)H(10)NO(4))](n), comprises polymeric chains whereby adjacent Sn atoms are bridged by carboxylate and amide carbonyl O atoms [Sn—O = 2.115 (15) and 2.653 (1) Å, respectively]. The Sn(IV) atom is five-coordinated showing a d...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793673/ https://www.ncbi.nlm.nih.gov/pubmed/24109260 http://dx.doi.org/10.1107/S1600536813017613 |
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author | Bhatti, Moazzam H. Yunus, Uzma Mussarat, Nosheen Helliwell, Madeleine Prendergast, Richard |
author_facet | Bhatti, Moazzam H. Yunus, Uzma Mussarat, Nosheen Helliwell, Madeleine Prendergast, Richard |
author_sort | Bhatti, Moazzam H. |
collection | PubMed |
description | The crystal structure of the polymeric title compound, [Sn(C(6)H(5))(3)(C(12)H(10)NO(4))](n), comprises polymeric chains whereby adjacent Sn atoms are bridged by carboxylate and amide carbonyl O atoms [Sn—O = 2.115 (15) and 2.653 (1) Å, respectively]. The Sn(IV) atom is five-coordinated showing a distorted trigonal–bipyramid geometry, with the three phenyl ipso-C atoms defining the trigonal plane and the axial positions occupied by O atoms [O—Sn—O = 171.91 (5)°]. Intramolecular N—H⋯O hydrogen bonding leads to a seven-membered loop. There is an intramolecular C—H⋯O interaction within the polymeric chain. An intermolecular C—H⋯O interaction along c links the polymeric chains into sheets which are linked into a three-dimensional network via C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3793673 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37936732013-10-09 catena-Poly[[triphenyltin(IV)]-μ-N-(4-acetylphenyl)maleamato] Bhatti, Moazzam H. Yunus, Uzma Mussarat, Nosheen Helliwell, Madeleine Prendergast, Richard Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the polymeric title compound, [Sn(C(6)H(5))(3)(C(12)H(10)NO(4))](n), comprises polymeric chains whereby adjacent Sn atoms are bridged by carboxylate and amide carbonyl O atoms [Sn—O = 2.115 (15) and 2.653 (1) Å, respectively]. The Sn(IV) atom is five-coordinated showing a distorted trigonal–bipyramid geometry, with the three phenyl ipso-C atoms defining the trigonal plane and the axial positions occupied by O atoms [O—Sn—O = 171.91 (5)°]. Intramolecular N—H⋯O hydrogen bonding leads to a seven-membered loop. There is an intramolecular C—H⋯O interaction within the polymeric chain. An intermolecular C—H⋯O interaction along c links the polymeric chains into sheets which are linked into a three-dimensional network via C—H⋯π interactions. International Union of Crystallography 2013-07-03 /pmc/articles/PMC3793673/ /pubmed/24109260 http://dx.doi.org/10.1107/S1600536813017613 Text en © Bhatti et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bhatti, Moazzam H. Yunus, Uzma Mussarat, Nosheen Helliwell, Madeleine Prendergast, Richard catena-Poly[[triphenyltin(IV)]-μ-N-(4-acetylphenyl)maleamato] |
title |
catena-Poly[[triphenyltin(IV)]-μ-N-(4-acetylphenyl)maleamato] |
title_full |
catena-Poly[[triphenyltin(IV)]-μ-N-(4-acetylphenyl)maleamato] |
title_fullStr |
catena-Poly[[triphenyltin(IV)]-μ-N-(4-acetylphenyl)maleamato] |
title_full_unstemmed |
catena-Poly[[triphenyltin(IV)]-μ-N-(4-acetylphenyl)maleamato] |
title_short |
catena-Poly[[triphenyltin(IV)]-μ-N-(4-acetylphenyl)maleamato] |
title_sort | catena-poly[[triphenyltin(iv)]-μ-n-(4-acetylphenyl)maleamato] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793673/ https://www.ncbi.nlm.nih.gov/pubmed/24109260 http://dx.doi.org/10.1107/S1600536813017613 |
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