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catena-Poly[[tri­phenyl­tin(IV)]-μ-N-(4-acetyl­phen­yl)maleamato]

The crystal structure of the polymeric title compound, [Sn(C(6)H(5))(3)(C(12)H(10)NO(4))](n), comprises polymeric chains whereby adjacent Sn atoms are bridged by carboxyl­ate and amide carbonyl O atoms [Sn—O = 2.115 (15) and 2.653 (1) Å, respectively]. The Sn(IV) atom is five-coordinated showing a d...

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Autores principales: Bhatti, Moazzam H., Yunus, Uzma, Mussarat, Nosheen, Helliwell, Madeleine, Prendergast, Richard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793673/
https://www.ncbi.nlm.nih.gov/pubmed/24109260
http://dx.doi.org/10.1107/S1600536813017613
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author Bhatti, Moazzam H.
Yunus, Uzma
Mussarat, Nosheen
Helliwell, Madeleine
Prendergast, Richard
author_facet Bhatti, Moazzam H.
Yunus, Uzma
Mussarat, Nosheen
Helliwell, Madeleine
Prendergast, Richard
author_sort Bhatti, Moazzam H.
collection PubMed
description The crystal structure of the polymeric title compound, [Sn(C(6)H(5))(3)(C(12)H(10)NO(4))](n), comprises polymeric chains whereby adjacent Sn atoms are bridged by carboxyl­ate and amide carbonyl O atoms [Sn—O = 2.115 (15) and 2.653 (1) Å, respectively]. The Sn(IV) atom is five-coordinated showing a distorted trigonal–bipyramid geometry, with the three phenyl ipso-C atoms defining the trigonal plane and the axial positions occupied by O atoms [O—Sn—O = 171.91 (5)°]. Intra­molecular N—H⋯O hydrogen bonding leads to a seven-membered loop. There is an intra­molecular C—H⋯O inter­action within the polymeric chain. An inter­molecular C—H⋯O inter­action along c links the polymeric chains into sheets which are linked into a three-dimensional network via C—H⋯π inter­actions.
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spelling pubmed-37936732013-10-09 catena-Poly[[tri­phenyl­tin(IV)]-μ-N-(4-acetyl­phen­yl)maleamato] Bhatti, Moazzam H. Yunus, Uzma Mussarat, Nosheen Helliwell, Madeleine Prendergast, Richard Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the polymeric title compound, [Sn(C(6)H(5))(3)(C(12)H(10)NO(4))](n), comprises polymeric chains whereby adjacent Sn atoms are bridged by carboxyl­ate and amide carbonyl O atoms [Sn—O = 2.115 (15) and 2.653 (1) Å, respectively]. The Sn(IV) atom is five-coordinated showing a distorted trigonal–bipyramid geometry, with the three phenyl ipso-C atoms defining the trigonal plane and the axial positions occupied by O atoms [O—Sn—O = 171.91 (5)°]. Intra­molecular N—H⋯O hydrogen bonding leads to a seven-membered loop. There is an intra­molecular C—H⋯O inter­action within the polymeric chain. An inter­molecular C—H⋯O inter­action along c links the polymeric chains into sheets which are linked into a three-dimensional network via C—H⋯π inter­actions. International Union of Crystallography 2013-07-03 /pmc/articles/PMC3793673/ /pubmed/24109260 http://dx.doi.org/10.1107/S1600536813017613 Text en © Bhatti et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bhatti, Moazzam H.
Yunus, Uzma
Mussarat, Nosheen
Helliwell, Madeleine
Prendergast, Richard
catena-Poly[[tri­phenyl­tin(IV)]-μ-N-(4-acetyl­phen­yl)maleamato]
title catena-Poly[[tri­phenyl­tin(IV)]-μ-N-(4-acetyl­phen­yl)maleamato]
title_full catena-Poly[[tri­phenyl­tin(IV)]-μ-N-(4-acetyl­phen­yl)maleamato]
title_fullStr catena-Poly[[tri­phenyl­tin(IV)]-μ-N-(4-acetyl­phen­yl)maleamato]
title_full_unstemmed catena-Poly[[tri­phenyl­tin(IV)]-μ-N-(4-acetyl­phen­yl)maleamato]
title_short catena-Poly[[tri­phenyl­tin(IV)]-μ-N-(4-acetyl­phen­yl)maleamato]
title_sort catena-poly[[tri­phenyl­tin(iv)]-μ-n-(4-acetyl­phen­yl)maleamato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793673/
https://www.ncbi.nlm.nih.gov/pubmed/24109260
http://dx.doi.org/10.1107/S1600536813017613
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