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Tris(2-formylphenolato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)samarium(III)
In the title compound, [Sm(C(7)H(5)O(2))(3)(C(12)H(8)N(2))], the Sm(III) cation is coordinated by six O atoms from three bidentate 2-formylphenolate ligands and by two N atoms from 1,10-phenanthroline ligand. The resulting SmN(2)O6 coordination polyhedron is a distorted square antiprism. In the cr...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793676/ https://www.ncbi.nlm.nih.gov/pubmed/24109263 http://dx.doi.org/10.1107/S1600536813016139 |
| Sumario: | In the title compound, [Sm(C(7)H(5)O(2))(3)(C(12)H(8)N(2))], the Sm(III) cation is coordinated by six O atoms from three bidentate 2-formylphenolate ligands and by two N atoms from 1,10-phenanthroline ligand. The resulting SmN(2)O6 coordination polyhedron is a distorted square antiprism. In the crystal, C—H⋯O interactions connect molecules into chains along the b-axis direction. In addition, π–π stacking interactions are observed with centroid–centroid distances in the range 3.6422 (13)–3.7329 (13) Å. |
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