Cargando…
Tris(2-formylphenolato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)samarium(III)
In the title compound, [Sm(C(7)H(5)O(2))(3)(C(12)H(8)N(2))], the Sm(III) cation is coordinated by six O atoms from three bidentate 2-formylphenolate ligands and by two N atoms from 1,10-phenanthroline ligand. The resulting SmN(2)O6 coordination polyhedron is a distorted square antiprism. In the cr...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793676/ https://www.ncbi.nlm.nih.gov/pubmed/24109263 http://dx.doi.org/10.1107/S1600536813016139 |
| _version_ | 1782287089150197760 |
|---|---|
| author | Zhong, Yun Yang, Jinbing Hu, Ling |
| author_facet | Zhong, Yun Yang, Jinbing Hu, Ling |
| author_sort | Zhong, Yun |
| collection | PubMed |
| description | In the title compound, [Sm(C(7)H(5)O(2))(3)(C(12)H(8)N(2))], the Sm(III) cation is coordinated by six O atoms from three bidentate 2-formylphenolate ligands and by two N atoms from 1,10-phenanthroline ligand. The resulting SmN(2)O6 coordination polyhedron is a distorted square antiprism. In the crystal, C—H⋯O interactions connect molecules into chains along the b-axis direction. In addition, π–π stacking interactions are observed with centroid–centroid distances in the range 3.6422 (13)–3.7329 (13) Å. |
| format | Online Article Text |
| id | pubmed-3793676 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-37936762013-10-09 Tris(2-formylphenolato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)samarium(III) Zhong, Yun Yang, Jinbing Hu, Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sm(C(7)H(5)O(2))(3)(C(12)H(8)N(2))], the Sm(III) cation is coordinated by six O atoms from three bidentate 2-formylphenolate ligands and by two N atoms from 1,10-phenanthroline ligand. The resulting SmN(2)O6 coordination polyhedron is a distorted square antiprism. In the crystal, C—H⋯O interactions connect molecules into chains along the b-axis direction. In addition, π–π stacking interactions are observed with centroid–centroid distances in the range 3.6422 (13)–3.7329 (13) Å. International Union of Crystallography 2013-07-03 /pmc/articles/PMC3793676/ /pubmed/24109263 http://dx.doi.org/10.1107/S1600536813016139 Text en © Zhong et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhong, Yun Yang, Jinbing Hu, Ling Tris(2-formylphenolato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)samarium(III) |
| title | Tris(2-formylphenolato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)samarium(III) |
| title_full | Tris(2-formylphenolato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)samarium(III) |
| title_fullStr | Tris(2-formylphenolato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)samarium(III) |
| title_full_unstemmed | Tris(2-formylphenolato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)samarium(III) |
| title_short | Tris(2-formylphenolato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)samarium(III) |
| title_sort | tris(2-formylphenolato-κ(2)
o,o′)(1,10-phenanthroline-κ(2)
n,n′)samarium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793676/ https://www.ncbi.nlm.nih.gov/pubmed/24109263 http://dx.doi.org/10.1107/S1600536813016139 |
| work_keys_str_mv | AT zhongyun tris2formylphenolatok2oo110phenanthrolinek2nnsamariumiii AT yangjinbing tris2formylphenolatok2oo110phenanthrolinek2nnsamariumiii AT huling tris2formylphenolatok2oo110phenanthrolinek2nnsamariumiii |