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Tetrakis(μ-3-chlorobenzoato-κ(2) O:O′)bis[(N,N-diethylnicotinamide-κN (1))copper(II)]
In the title centrosymmetric binuclear Cu(II) complex, [Cu(2)(C(7)H(4)ClO(2))(4)(C(10)H(14)N(2)O)(2)], the two Cu(II) cations [Cu⋯Cu = 2.6314 (4) Å] are bridged by four 3-chlorobenzoate (CB) anions. The four carboxylate O atoms around each Cu(II) cation form a distorted square-planar arrangement,...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793677/ https://www.ncbi.nlm.nih.gov/pubmed/24109264 http://dx.doi.org/10.1107/S1600536813017881 |
Sumario: | In the title centrosymmetric binuclear Cu(II) complex, [Cu(2)(C(7)H(4)ClO(2))(4)(C(10)H(14)N(2)O)(2)], the two Cu(II) cations [Cu⋯Cu = 2.6314 (4) Å] are bridged by four 3-chlorobenzoate (CB) anions. The four carboxylate O atoms around each Cu(II) cation form a distorted square-planar arrangement, the distorted square-pyramidal coordination geometry being completed by the pyridine N atom of the N,N-diethylnicotinamide (DENA) molecule. The dihedral angle between the benzene ring and the carboxylate group is 4.49 (11)° in one of the independent CB ligands and 12.00 (10)° in the other. The benzene rings of the independent CB ligands are oriented at a dihedral angle of 84.13 (6)°. In the crystal, weak C—H⋯O hydrogen bonds link the binuclear complex molecules into supramolecular chains running along [101]. |
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