Cargando…
Tetrakis(μ-3-chlorobenzoato-κ(2) O:O′)bis[(N,N-diethylnicotinamide-κN (1))copper(II)]
In the title centrosymmetric binuclear Cu(II) complex, [Cu(2)(C(7)H(4)ClO(2))(4)(C(10)H(14)N(2)O)(2)], the two Cu(II) cations [Cu⋯Cu = 2.6314 (4) Å] are bridged by four 3-chlorobenzoate (CB) anions. The four carboxylate O atoms around each Cu(II) cation form a distorted square-planar arrangement,...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793677/ https://www.ncbi.nlm.nih.gov/pubmed/24109264 http://dx.doi.org/10.1107/S1600536813017881 |
_version_ | 1782287089435410432 |
---|---|
author | Bozkurt, Nihat Tunç, Tuncay Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_facet | Bozkurt, Nihat Tunç, Tuncay Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_sort | Bozkurt, Nihat |
collection | PubMed |
description | In the title centrosymmetric binuclear Cu(II) complex, [Cu(2)(C(7)H(4)ClO(2))(4)(C(10)H(14)N(2)O)(2)], the two Cu(II) cations [Cu⋯Cu = 2.6314 (4) Å] are bridged by four 3-chlorobenzoate (CB) anions. The four carboxylate O atoms around each Cu(II) cation form a distorted square-planar arrangement, the distorted square-pyramidal coordination geometry being completed by the pyridine N atom of the N,N-diethylnicotinamide (DENA) molecule. The dihedral angle between the benzene ring and the carboxylate group is 4.49 (11)° in one of the independent CB ligands and 12.00 (10)° in the other. The benzene rings of the independent CB ligands are oriented at a dihedral angle of 84.13 (6)°. In the crystal, weak C—H⋯O hydrogen bonds link the binuclear complex molecules into supramolecular chains running along [101]. |
format | Online Article Text |
id | pubmed-3793677 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37936772013-10-09 Tetrakis(μ-3-chlorobenzoato-κ(2) O:O′)bis[(N,N-diethylnicotinamide-κN (1))copper(II)] Bozkurt, Nihat Tunç, Tuncay Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric binuclear Cu(II) complex, [Cu(2)(C(7)H(4)ClO(2))(4)(C(10)H(14)N(2)O)(2)], the two Cu(II) cations [Cu⋯Cu = 2.6314 (4) Å] are bridged by four 3-chlorobenzoate (CB) anions. The four carboxylate O atoms around each Cu(II) cation form a distorted square-planar arrangement, the distorted square-pyramidal coordination geometry being completed by the pyridine N atom of the N,N-diethylnicotinamide (DENA) molecule. The dihedral angle between the benzene ring and the carboxylate group is 4.49 (11)° in one of the independent CB ligands and 12.00 (10)° in the other. The benzene rings of the independent CB ligands are oriented at a dihedral angle of 84.13 (6)°. In the crystal, weak C—H⋯O hydrogen bonds link the binuclear complex molecules into supramolecular chains running along [101]. International Union of Crystallography 2013-07-03 /pmc/articles/PMC3793677/ /pubmed/24109264 http://dx.doi.org/10.1107/S1600536813017881 Text en © Bozkurt et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bozkurt, Nihat Tunç, Tuncay Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Tetrakis(μ-3-chlorobenzoato-κ(2) O:O′)bis[(N,N-diethylnicotinamide-κN (1))copper(II)] |
title | Tetrakis(μ-3-chlorobenzoato-κ(2)
O:O′)bis[(N,N-diethylnicotinamide-κN
(1))copper(II)] |
title_full | Tetrakis(μ-3-chlorobenzoato-κ(2)
O:O′)bis[(N,N-diethylnicotinamide-κN
(1))copper(II)] |
title_fullStr | Tetrakis(μ-3-chlorobenzoato-κ(2)
O:O′)bis[(N,N-diethylnicotinamide-κN
(1))copper(II)] |
title_full_unstemmed | Tetrakis(μ-3-chlorobenzoato-κ(2)
O:O′)bis[(N,N-diethylnicotinamide-κN
(1))copper(II)] |
title_short | Tetrakis(μ-3-chlorobenzoato-κ(2)
O:O′)bis[(N,N-diethylnicotinamide-κN
(1))copper(II)] |
title_sort | tetrakis(μ-3-chlorobenzoato-κ(2)
o:o′)bis[(n,n-diethylnicotinamide-κn
(1))copper(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793677/ https://www.ncbi.nlm.nih.gov/pubmed/24109264 http://dx.doi.org/10.1107/S1600536813017881 |
work_keys_str_mv | AT bozkurtnihat tetrakism3chlorobenzoatok2oobisnndiethylnicotinamidekn1copperii AT tunctuncay tetrakism3chlorobenzoatok2oobisnndiethylnicotinamidekn1copperii AT caylakdelibasnagihan tetrakism3chlorobenzoatok2oobisnndiethylnicotinamidekn1copperii AT necefogluhacali tetrakism3chlorobenzoatok2oobisnndiethylnicotinamidekn1copperii AT hokelektuncer tetrakism3chlorobenzoatok2oobisnndiethylnicotinamidekn1copperii |