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Tetra­kis(μ-3-chloro­benzoato-κ(2) O:O′)bis­[(N,N-di­ethyl­nicotinamide-κN (1))copper(II)]

In the title centrosymmetric binuclear Cu(II) complex, [Cu(2)(C(7)H(4)ClO(2))(4)(C(10)H(14)N(2)O)(2)], the two Cu(II) cations [Cu⋯Cu = 2.6314 (4) Å] are bridged by four 3-chloro­benzoate (CB) anions. The four carboxyl­ate O atoms around each Cu(II) cation form a distorted square-planar arrangement,...

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Autores principales: Bozkurt, Nihat, Tunç, Tuncay, Çaylak Delibaş, Nagihan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793677/
https://www.ncbi.nlm.nih.gov/pubmed/24109264
http://dx.doi.org/10.1107/S1600536813017881
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author Bozkurt, Nihat
Tunç, Tuncay
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_facet Bozkurt, Nihat
Tunç, Tuncay
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_sort Bozkurt, Nihat
collection PubMed
description In the title centrosymmetric binuclear Cu(II) complex, [Cu(2)(C(7)H(4)ClO(2))(4)(C(10)H(14)N(2)O)(2)], the two Cu(II) cations [Cu⋯Cu = 2.6314 (4) Å] are bridged by four 3-chloro­benzoate (CB) anions. The four carboxyl­ate O atoms around each Cu(II) cation form a distorted square-planar arrangement, the distorted square-pyramidal coordination geometry being completed by the pyridine N atom of the N,N-di­ethyl­nicotinamide (DENA) mol­ecule. The dihedral angle between the benzene ring and the carboxyl­ate group is 4.49 (11)° in one of the independent CB ligands and 12.00 (10)° in the other. The benzene rings of the independent CB ligands are oriented at a dihedral angle of 84.13 (6)°. In the crystal, weak C—H⋯O hydrogen bonds link the binuclear complex mol­ecules into supra­molecular chains running along [101].
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spelling pubmed-37936772013-10-09 Tetra­kis(μ-3-chloro­benzoato-κ(2) O:O′)bis­[(N,N-di­ethyl­nicotinamide-κN (1))copper(II)] Bozkurt, Nihat Tunç, Tuncay Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric binuclear Cu(II) complex, [Cu(2)(C(7)H(4)ClO(2))(4)(C(10)H(14)N(2)O)(2)], the two Cu(II) cations [Cu⋯Cu = 2.6314 (4) Å] are bridged by four 3-chloro­benzoate (CB) anions. The four carboxyl­ate O atoms around each Cu(II) cation form a distorted square-planar arrangement, the distorted square-pyramidal coordination geometry being completed by the pyridine N atom of the N,N-di­ethyl­nicotinamide (DENA) mol­ecule. The dihedral angle between the benzene ring and the carboxyl­ate group is 4.49 (11)° in one of the independent CB ligands and 12.00 (10)° in the other. The benzene rings of the independent CB ligands are oriented at a dihedral angle of 84.13 (6)°. In the crystal, weak C—H⋯O hydrogen bonds link the binuclear complex mol­ecules into supra­molecular chains running along [101]. International Union of Crystallography 2013-07-03 /pmc/articles/PMC3793677/ /pubmed/24109264 http://dx.doi.org/10.1107/S1600536813017881 Text en © Bozkurt et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bozkurt, Nihat
Tunç, Tuncay
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
Tetra­kis(μ-3-chloro­benzoato-κ(2) O:O′)bis­[(N,N-di­ethyl­nicotinamide-κN (1))copper(II)]
title Tetra­kis(μ-3-chloro­benzoato-κ(2) O:O′)bis­[(N,N-di­ethyl­nicotinamide-κN (1))copper(II)]
title_full Tetra­kis(μ-3-chloro­benzoato-κ(2) O:O′)bis­[(N,N-di­ethyl­nicotinamide-κN (1))copper(II)]
title_fullStr Tetra­kis(μ-3-chloro­benzoato-κ(2) O:O′)bis­[(N,N-di­ethyl­nicotinamide-κN (1))copper(II)]
title_full_unstemmed Tetra­kis(μ-3-chloro­benzoato-κ(2) O:O′)bis­[(N,N-di­ethyl­nicotinamide-κN (1))copper(II)]
title_short Tetra­kis(μ-3-chloro­benzoato-κ(2) O:O′)bis­[(N,N-di­ethyl­nicotinamide-κN (1))copper(II)]
title_sort tetra­kis(μ-3-chloro­benzoato-κ(2) o:o′)bis­[(n,n-di­ethyl­nicotinamide-κn (1))copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793677/
https://www.ncbi.nlm.nih.gov/pubmed/24109264
http://dx.doi.org/10.1107/S1600536813017881
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