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{2-[2,2-Bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl-κN)propyl]pyridine}dichloridoiron(II)
The title compound,[FeCl(2)(C(18)H(25)N(3)O(2))], has a distorted tetrahedral Cl(2)N(2) coordination of the Fe(II) atom as a result of the constraints imposed by the 2-[2,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)propyl]pyridine ligand. The pyridine ring is almost perpendicular to the six-m...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793678/ https://www.ncbi.nlm.nih.gov/pubmed/24109265 http://dx.doi.org/10.1107/S1600536813018047 |
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author | Roviello, Giuseppina Tuzi, Angela Capacchione, Carmine Milione, Stefano Ferone, Claudio |
author_facet | Roviello, Giuseppina Tuzi, Angela Capacchione, Carmine Milione, Stefano Ferone, Claudio |
author_sort | Roviello, Giuseppina |
collection | PubMed |
description | The title compound,[FeCl(2)(C(18)H(25)N(3)O(2))], has a distorted tetrahedral Cl(2)N(2) coordination of the Fe(II) atom as a result of the constraints imposed by the 2-[2,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)propyl]pyridine ligand. The pyridine ring is almost perpendicular to the six-membered chelated ring containing the metal atom [dihedral angle between their mean planes = 88.5 (1)°]. |
format | Online Article Text |
id | pubmed-3793678 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37936782013-10-09 {2-[2,2-Bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl-κN)propyl]pyridine}dichloridoiron(II) Roviello, Giuseppina Tuzi, Angela Capacchione, Carmine Milione, Stefano Ferone, Claudio Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound,[FeCl(2)(C(18)H(25)N(3)O(2))], has a distorted tetrahedral Cl(2)N(2) coordination of the Fe(II) atom as a result of the constraints imposed by the 2-[2,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)propyl]pyridine ligand. The pyridine ring is almost perpendicular to the six-membered chelated ring containing the metal atom [dihedral angle between their mean planes = 88.5 (1)°]. International Union of Crystallography 2013-07-06 /pmc/articles/PMC3793678/ /pubmed/24109265 http://dx.doi.org/10.1107/S1600536813018047 Text en © Roviello et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Roviello, Giuseppina Tuzi, Angela Capacchione, Carmine Milione, Stefano Ferone, Claudio {2-[2,2-Bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl-κN)propyl]pyridine}dichloridoiron(II) |
title | {2-[2,2-Bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl-κN)propyl]pyridine}dichloridoiron(II) |
title_full | {2-[2,2-Bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl-κN)propyl]pyridine}dichloridoiron(II) |
title_fullStr | {2-[2,2-Bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl-κN)propyl]pyridine}dichloridoiron(II) |
title_full_unstemmed | {2-[2,2-Bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl-κN)propyl]pyridine}dichloridoiron(II) |
title_short | {2-[2,2-Bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl-κN)propyl]pyridine}dichloridoiron(II) |
title_sort | {2-[2,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl-κn)propyl]pyridine}dichloridoiron(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793678/ https://www.ncbi.nlm.nih.gov/pubmed/24109265 http://dx.doi.org/10.1107/S1600536813018047 |
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