catena-Poly[heptyl­enedi­ammonium [[tetra­chloridobismuthate(III)]-μ-chlorido]]

The title organic-inorganic hybrid compound, {(C(7)H(20)N(2))[BiCl(5)]}(n), consists of distorted corner-joined [BiCl(6)] octa­hedra forming zigzag polymeric anionic chains parallel to [001], separated by columns of heptyl­enedi­ammonium cations. The asymmetric unit contains two crystallographically...

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Detalles Bibliográficos
Autores principales: Ouasri, Ali, Rhandour, Ali, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793680/
https://www.ncbi.nlm.nih.gov/pubmed/24109267
http://dx.doi.org/10.1107/S1600536813018102
Descripción
Sumario:The title organic-inorganic hybrid compound, {(C(7)H(20)N(2))[BiCl(5)]}(n), consists of distorted corner-joined [BiCl(6)] octa­hedra forming zigzag polymeric anionic chains parallel to [001], separated by columns of heptyl­enedi­ammonium cations. The asymmetric unit contains two crystallographically independent bis­muth metal atoms, one of which lies on an inversion centre and the other on a twofold axis. In the crystal, the polymeric chains and cations are linked by N—H⋯Cl hydrogen bonds, forming undulating layers parallel to (110).

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