catena-Poly[heptyl­enedi­ammonium [[tetra­chloridobismuthate(III)]-μ-chlorido]]

The title organic-inorganic hybrid compound, {(C(7)H(20)N(2))[BiCl(5)]}(n), consists of distorted corner-joined [BiCl(6)] octa­hedra forming zigzag polymeric anionic chains parallel to [001], separated by columns of heptyl­enedi­ammonium cations. The asymmetric unit contains two crystallographically...

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Detalles Bibliográficos
Autores principales: Ouasri, Ali, Rhandour, Ali, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793680/
https://www.ncbi.nlm.nih.gov/pubmed/24109267
http://dx.doi.org/10.1107/S1600536813018102
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author Ouasri, Ali
Rhandour, Ali
Saadi, Mohamed
El Ammari, Lahcen
author_facet Ouasri, Ali
Rhandour, Ali
Saadi, Mohamed
El Ammari, Lahcen
author_sort Ouasri, Ali
collection PubMed
description The title organic-inorganic hybrid compound, {(C(7)H(20)N(2))[BiCl(5)]}(n), consists of distorted corner-joined [BiCl(6)] octa­hedra forming zigzag polymeric anionic chains parallel to [001], separated by columns of heptyl­enedi­ammonium cations. The asymmetric unit contains two crystallographically independent bis­muth metal atoms, one of which lies on an inversion centre and the other on a twofold axis. In the crystal, the polymeric chains and cations are linked by N—H⋯Cl hydrogen bonds, forming undulating layers parallel to (110).
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spelling pubmed-37936802013-10-09 catena-Poly[heptyl­enedi­ammonium [[tetra­chloridobismuthate(III)]-μ-chlorido]] Ouasri, Ali Rhandour, Ali Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title organic-inorganic hybrid compound, {(C(7)H(20)N(2))[BiCl(5)]}(n), consists of distorted corner-joined [BiCl(6)] octa­hedra forming zigzag polymeric anionic chains parallel to [001], separated by columns of heptyl­enedi­ammonium cations. The asymmetric unit contains two crystallographically independent bis­muth metal atoms, one of which lies on an inversion centre and the other on a twofold axis. In the crystal, the polymeric chains and cations are linked by N—H⋯Cl hydrogen bonds, forming undulating layers parallel to (110). International Union of Crystallography 2013-07-06 /pmc/articles/PMC3793680/ /pubmed/24109267 http://dx.doi.org/10.1107/S1600536813018102 Text en © Ouasri et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ouasri, Ali
Rhandour, Ali
Saadi, Mohamed
El Ammari, Lahcen
catena-Poly[heptyl­enedi­ammonium [[tetra­chloridobismuthate(III)]-μ-chlorido]]
title catena-Poly[heptyl­enedi­ammonium [[tetra­chloridobismuthate(III)]-μ-chlorido]]
title_full catena-Poly[heptyl­enedi­ammonium [[tetra­chloridobismuthate(III)]-μ-chlorido]]
title_fullStr catena-Poly[heptyl­enedi­ammonium [[tetra­chloridobismuthate(III)]-μ-chlorido]]
title_full_unstemmed catena-Poly[heptyl­enedi­ammonium [[tetra­chloridobismuthate(III)]-μ-chlorido]]
title_short catena-Poly[heptyl­enedi­ammonium [[tetra­chloridobismuthate(III)]-μ-chlorido]]
title_sort catena-poly[heptyl­enedi­ammonium [[tetra­chloridobismuthate(iii)]-μ-chlorido]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793680/
https://www.ncbi.nlm.nih.gov/pubmed/24109267
http://dx.doi.org/10.1107/S1600536813018102
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