Tri­aqua­(pyrazole-4-carboxyl­ato-κN (1))lithium

In the monomeric title complex, [Li(C(4)H(3)N(2)O(2))(H(2)O)(3)], the Li(+) cation is coordinated by a pyrazole N atom and three water mol­ecules in a distorted tetra­hedral geometry. The carboxyl­ate group is deprotonated. The complex mol­ecules are involved in O—H⋯O and N—H⋯O hydrogen bonding, for...

Descripción completa

Detalles Bibliográficos
Autores principales: Starosta, Wojciech, Leciejewicz, Janusz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793681/
https://www.ncbi.nlm.nih.gov/pubmed/24109268
http://dx.doi.org/10.1107/S160053681301831X
Descripción
Sumario:In the monomeric title complex, [Li(C(4)H(3)N(2)O(2))(H(2)O)(3)], the Li(+) cation is coordinated by a pyrazole N atom and three water mol­ecules in a distorted tetra­hedral geometry. The carboxyl­ate group is deprotonated. The complex mol­ecules are involved in O—H⋯O and N—H⋯O hydrogen bonding, forming layers stacked along the b axis.

Ejemplares similares