Tri­aqua­(pyrazole-4-carboxyl­ato-κN (1))lithium

In the monomeric title complex, [Li(C(4)H(3)N(2)O(2))(H(2)O)(3)], the Li(+) cation is coordinated by a pyrazole N atom and three water mol­ecules in a distorted tetra­hedral geometry. The carboxyl­ate group is deprotonated. The complex mol­ecules are involved in O—H⋯O and N—H⋯O hydrogen bonding, for...

Descripción completa

Detalles Bibliográficos
Autores principales: Starosta, Wojciech, Leciejewicz, Janusz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793681/
https://www.ncbi.nlm.nih.gov/pubmed/24109268
http://dx.doi.org/10.1107/S160053681301831X
_version_ 1782287090437849088
author Starosta, Wojciech
Leciejewicz, Janusz
author_facet Starosta, Wojciech
Leciejewicz, Janusz
author_sort Starosta, Wojciech
collection PubMed
description In the monomeric title complex, [Li(C(4)H(3)N(2)O(2))(H(2)O)(3)], the Li(+) cation is coordinated by a pyrazole N atom and three water mol­ecules in a distorted tetra­hedral geometry. The carboxyl­ate group is deprotonated. The complex mol­ecules are involved in O—H⋯O and N—H⋯O hydrogen bonding, forming layers stacked along the b axis.
format Online
Article
Text
id pubmed-3793681
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-37936812013-10-09 Tri­aqua­(pyrazole-4-carboxyl­ato-κN (1))lithium Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the monomeric title complex, [Li(C(4)H(3)N(2)O(2))(H(2)O)(3)], the Li(+) cation is coordinated by a pyrazole N atom and three water mol­ecules in a distorted tetra­hedral geometry. The carboxyl­ate group is deprotonated. The complex mol­ecules are involved in O—H⋯O and N—H⋯O hydrogen bonding, forming layers stacked along the b axis. International Union of Crystallography 2013-07-06 /pmc/articles/PMC3793681/ /pubmed/24109268 http://dx.doi.org/10.1107/S160053681301831X Text en © Starosta and Leciejewicz 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Starosta, Wojciech
Leciejewicz, Janusz
Tri­aqua­(pyrazole-4-carboxyl­ato-κN (1))lithium
title Tri­aqua­(pyrazole-4-carboxyl­ato-κN (1))lithium
title_full Tri­aqua­(pyrazole-4-carboxyl­ato-κN (1))lithium
title_fullStr Tri­aqua­(pyrazole-4-carboxyl­ato-κN (1))lithium
title_full_unstemmed Tri­aqua­(pyrazole-4-carboxyl­ato-κN (1))lithium
title_short Tri­aqua­(pyrazole-4-carboxyl­ato-κN (1))lithium
title_sort tri­aqua­(pyrazole-4-carboxyl­ato-κn (1))lithium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793681/
https://www.ncbi.nlm.nih.gov/pubmed/24109268
http://dx.doi.org/10.1107/S160053681301831X
work_keys_str_mv AT starostawojciech triaquapyrazole4carboxylatokn1lithium
AT leciejewiczjanusz triaquapyrazole4carboxylatokn1lithium

Ejemplares similares