Di­aqua­bis­[2-(2-hy­droxy­eth­yl)pyridine-κ(2) N,O]cobalt(II) dichloride

In the title salt, [Co(C(7)H(9)NO)(2)(H(2)O)(2)]Cl(2), the Co(II) cation, located on an inversion center, is N,O-chelated by two hy­droxy­ethyl­pyridine ligands and coordinated by two water mol­ecules in a distorted O(4)N(2) octa­hedral geometry. In the crystal, the Cl(−) anions link with the comple...

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Autores principales: Zeghouan, Ouahida, Guenifa, Fatiha, Hadjadj, Nasreddine, Bendjeddou, Lamia, Merazig, Hocine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793682/
https://www.ncbi.nlm.nih.gov/pubmed/24109269
http://dx.doi.org/10.1107/S1600536813018321
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author Zeghouan, Ouahida
Guenifa, Fatiha
Hadjadj, Nasreddine
Bendjeddou, Lamia
Merazig, Hocine
author_facet Zeghouan, Ouahida
Guenifa, Fatiha
Hadjadj, Nasreddine
Bendjeddou, Lamia
Merazig, Hocine
author_sort Zeghouan, Ouahida
collection PubMed
description In the title salt, [Co(C(7)H(9)NO)(2)(H(2)O)(2)]Cl(2), the Co(II) cation, located on an inversion center, is N,O-chelated by two hy­droxy­ethyl­pyridine ligands and coordinated by two water mol­ecules in a distorted O(4)N(2) octa­hedral geometry. In the crystal, the Cl(−) anions link with the complex cations via O—H⋯Cl hydrogen bonds, forming a three-dimensional supra­molecular architecture. π–π stacking is observed between the pyridine rings of adjacent mol­ecules [centroid–centroid distance = 3.5810 (11) Å].
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spelling pubmed-37936822013-10-09 Di­aqua­bis­[2-(2-hy­droxy­eth­yl)pyridine-κ(2) N,O]cobalt(II) dichloride Zeghouan, Ouahida Guenifa, Fatiha Hadjadj, Nasreddine Bendjeddou, Lamia Merazig, Hocine Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [Co(C(7)H(9)NO)(2)(H(2)O)(2)]Cl(2), the Co(II) cation, located on an inversion center, is N,O-chelated by two hy­droxy­ethyl­pyridine ligands and coordinated by two water mol­ecules in a distorted O(4)N(2) octa­hedral geometry. In the crystal, the Cl(−) anions link with the complex cations via O—H⋯Cl hydrogen bonds, forming a three-dimensional supra­molecular architecture. π–π stacking is observed between the pyridine rings of adjacent mol­ecules [centroid–centroid distance = 3.5810 (11) Å]. International Union of Crystallography 2013-07-06 /pmc/articles/PMC3793682/ /pubmed/24109269 http://dx.doi.org/10.1107/S1600536813018321 Text en © Zeghouan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zeghouan, Ouahida
Guenifa, Fatiha
Hadjadj, Nasreddine
Bendjeddou, Lamia
Merazig, Hocine
Di­aqua­bis­[2-(2-hy­droxy­eth­yl)pyridine-κ(2) N,O]cobalt(II) dichloride
title Di­aqua­bis­[2-(2-hy­droxy­eth­yl)pyridine-κ(2) N,O]cobalt(II) dichloride
title_full Di­aqua­bis­[2-(2-hy­droxy­eth­yl)pyridine-κ(2) N,O]cobalt(II) dichloride
title_fullStr Di­aqua­bis­[2-(2-hy­droxy­eth­yl)pyridine-κ(2) N,O]cobalt(II) dichloride
title_full_unstemmed Di­aqua­bis­[2-(2-hy­droxy­eth­yl)pyridine-κ(2) N,O]cobalt(II) dichloride
title_short Di­aqua­bis­[2-(2-hy­droxy­eth­yl)pyridine-κ(2) N,O]cobalt(II) dichloride
title_sort di­aqua­bis­[2-(2-hy­droxy­eth­yl)pyridine-κ(2) n,o]cobalt(ii) dichloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793682/
https://www.ncbi.nlm.nih.gov/pubmed/24109269
http://dx.doi.org/10.1107/S1600536813018321
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