Trichlorido(1,3-dimethyl-2,3-di­hydro-1H-imidazol-2-yl­idene-κC (2))aluminium(III)

The title compound, [Al(C(5)H(8)N(2))Cl(3)], was prepared by a thermolytic decomposition under high-vacuum conditions and presents a formal adduct of an Arduengo carbene, 1,3-dimethyl-1H-imidazol-2-yl­idene, and aluminium trichloride. The Al atom adopts a pseudo-tetra­hedral CCl(3) coordination envi...

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Autores principales: Tian, Chong, Gao, Xiaofei, Chen, Qiao, Nie, Wanli, Borzov, Maxim V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793683/
https://www.ncbi.nlm.nih.gov/pubmed/24109270
http://dx.doi.org/10.1107/S1600536813018254
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author Tian, Chong
Gao, Xiaofei
Chen, Qiao
Nie, Wanli
Borzov, Maxim V.
author_facet Tian, Chong
Gao, Xiaofei
Chen, Qiao
Nie, Wanli
Borzov, Maxim V.
author_sort Tian, Chong
collection PubMed
description The title compound, [Al(C(5)H(8)N(2))Cl(3)], was prepared by a thermolytic decomposition under high-vacuum conditions and presents a formal adduct of an Arduengo carbene, 1,3-dimethyl-1H-imidazol-2-yl­idene, and aluminium trichloride. The Al atom adopts a pseudo-tetra­hedral CCl(3) coordination environment. All N and C atoms, the Al atom, one of the Cl atoms, and all aromatic H atoms of the mol­ecule lie on a mirror plane. As a result of the mirror symmetry of the mol­ecule, the H atoms of all methyl groups are disordered between symmetry-equivalent positions.
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spelling pubmed-37936832013-10-09 Trichlorido(1,3-dimethyl-2,3-di­hydro-1H-imidazol-2-yl­idene-κC (2))aluminium(III) Tian, Chong Gao, Xiaofei Chen, Qiao Nie, Wanli Borzov, Maxim V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Al(C(5)H(8)N(2))Cl(3)], was prepared by a thermolytic decomposition under high-vacuum conditions and presents a formal adduct of an Arduengo carbene, 1,3-dimethyl-1H-imidazol-2-yl­idene, and aluminium trichloride. The Al atom adopts a pseudo-tetra­hedral CCl(3) coordination environment. All N and C atoms, the Al atom, one of the Cl atoms, and all aromatic H atoms of the mol­ecule lie on a mirror plane. As a result of the mirror symmetry of the mol­ecule, the H atoms of all methyl groups are disordered between symmetry-equivalent positions. International Union of Crystallography 2013-07-06 /pmc/articles/PMC3793683/ /pubmed/24109270 http://dx.doi.org/10.1107/S1600536813018254 Text en © Tian et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tian, Chong
Gao, Xiaofei
Chen, Qiao
Nie, Wanli
Borzov, Maxim V.
Trichlorido(1,3-dimethyl-2,3-di­hydro-1H-imidazol-2-yl­idene-κC (2))aluminium(III)
title Trichlorido(1,3-dimethyl-2,3-di­hydro-1H-imidazol-2-yl­idene-κC (2))aluminium(III)
title_full Trichlorido(1,3-dimethyl-2,3-di­hydro-1H-imidazol-2-yl­idene-κC (2))aluminium(III)
title_fullStr Trichlorido(1,3-dimethyl-2,3-di­hydro-1H-imidazol-2-yl­idene-κC (2))aluminium(III)
title_full_unstemmed Trichlorido(1,3-dimethyl-2,3-di­hydro-1H-imidazol-2-yl­idene-κC (2))aluminium(III)
title_short Trichlorido(1,3-dimethyl-2,3-di­hydro-1H-imidazol-2-yl­idene-κC (2))aluminium(III)
title_sort trichlorido(1,3-dimethyl-2,3-di­hydro-1h-imidazol-2-yl­idene-κc (2))aluminium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793683/
https://www.ncbi.nlm.nih.gov/pubmed/24109270
http://dx.doi.org/10.1107/S1600536813018254
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AT niewanli trichlorido13dimethyl23dihydro1himidazol2ylidenekc2aluminiumiii
AT borzovmaximv trichlorido13dimethyl23dihydro1himidazol2ylidenekc2aluminiumiii

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