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Bis[2-(1,3-benzothiazol-2-yl)phenyl-κ(2) C (1),N][1,3-bis(4-bromophenyl)propane-1,3-dionato-κ(2) O,O′]iridium(III)
The title complex, [Ir(C(15)H(9)Br(2)O(2))(C(13)H(8)NS)(2)], lies about a crystallographic twofold rotation axis passing through the Ir(III) atom and the central C atom of the bis(bromophenyl)propane-1,3-dionate ligand. The Ir(III) atom adopts a distorted octahedral geometry coordinated by two N...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793684/ https://www.ncbi.nlm.nih.gov/pubmed/24109271 http://dx.doi.org/10.1107/S1600536813018394 |
| _version_ | 1782287091148783616 |
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| author | Kim, Young-Inn Yun, Seong-Jae Kang, Sung Kwon |
| author_facet | Kim, Young-Inn Yun, Seong-Jae Kang, Sung Kwon |
| author_sort | Kim, Young-Inn |
| collection | PubMed |
| description | The title complex, [Ir(C(15)H(9)Br(2)O(2))(C(13)H(8)NS)(2)], lies about a crystallographic twofold rotation axis passing through the Ir(III) atom and the central C atom of the bis(bromophenyl)propane-1,3-dionate ligand. The Ir(III) atom adopts a distorted octahedral geometry coordinated by two N atoms in the axial positions, and two C and two O atoms in the equatorial plane. The dihedral angle between the two thiazole ring systems in the complex is 77.45 (10)°. |
| format | Online Article Text |
| id | pubmed-3793684 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-37936842013-10-09 Bis[2-(1,3-benzothiazol-2-yl)phenyl-κ(2) C (1),N][1,3-bis(4-bromophenyl)propane-1,3-dionato-κ(2) O,O′]iridium(III) Kim, Young-Inn Yun, Seong-Jae Kang, Sung Kwon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Ir(C(15)H(9)Br(2)O(2))(C(13)H(8)NS)(2)], lies about a crystallographic twofold rotation axis passing through the Ir(III) atom and the central C atom of the bis(bromophenyl)propane-1,3-dionate ligand. The Ir(III) atom adopts a distorted octahedral geometry coordinated by two N atoms in the axial positions, and two C and two O atoms in the equatorial plane. The dihedral angle between the two thiazole ring systems in the complex is 77.45 (10)°. International Union of Crystallography 2013-07-10 /pmc/articles/PMC3793684/ /pubmed/24109271 http://dx.doi.org/10.1107/S1600536813018394 Text en © Kim et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kim, Young-Inn Yun, Seong-Jae Kang, Sung Kwon Bis[2-(1,3-benzothiazol-2-yl)phenyl-κ(2) C (1),N][1,3-bis(4-bromophenyl)propane-1,3-dionato-κ(2) O,O′]iridium(III) |
| title | Bis[2-(1,3-benzothiazol-2-yl)phenyl-κ(2)
C
(1),N][1,3-bis(4-bromophenyl)propane-1,3-dionato-κ(2)
O,O′]iridium(III) |
| title_full | Bis[2-(1,3-benzothiazol-2-yl)phenyl-κ(2)
C
(1),N][1,3-bis(4-bromophenyl)propane-1,3-dionato-κ(2)
O,O′]iridium(III) |
| title_fullStr | Bis[2-(1,3-benzothiazol-2-yl)phenyl-κ(2)
C
(1),N][1,3-bis(4-bromophenyl)propane-1,3-dionato-κ(2)
O,O′]iridium(III) |
| title_full_unstemmed | Bis[2-(1,3-benzothiazol-2-yl)phenyl-κ(2)
C
(1),N][1,3-bis(4-bromophenyl)propane-1,3-dionato-κ(2)
O,O′]iridium(III) |
| title_short | Bis[2-(1,3-benzothiazol-2-yl)phenyl-κ(2)
C
(1),N][1,3-bis(4-bromophenyl)propane-1,3-dionato-κ(2)
O,O′]iridium(III) |
| title_sort | bis[2-(1,3-benzothiazol-2-yl)phenyl-κ(2)
c
(1),n][1,3-bis(4-bromophenyl)propane-1,3-dionato-κ(2)
o,o′]iridium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793684/ https://www.ncbi.nlm.nih.gov/pubmed/24109271 http://dx.doi.org/10.1107/S1600536813018394 |
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