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(2,2′-Bipyridine-κ(2) N,N′)tetrakis(dimethyl sulfoxide-κO)copper(II) bis(perchlorate)
The title compound, [Cu(C(2)H(6)OS)(4)(C(10)H(8)N(2))](ClO(4))(2), contains a Cu(II) ion with a distorted octahedral coordination environment, bonded by four O atoms of the monodentate dimethyl sulfoxide ligands and two N atoms of the bidentate chelating 2,2′-bipyridine ligand. The equatorial Cu—N...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793687/ https://www.ncbi.nlm.nih.gov/pubmed/24109274 http://dx.doi.org/10.1107/S1600536813018485 |
Sumario: | The title compound, [Cu(C(2)H(6)OS)(4)(C(10)H(8)N(2))](ClO(4))(2), contains a Cu(II) ion with a distorted octahedral coordination environment, bonded by four O atoms of the monodentate dimethyl sulfoxide ligands and two N atoms of the bidentate chelating 2,2′-bipyridine ligand. The equatorial Cu—N and Cu—O bond lengths are in the range 1.979 (2)-1.998 (3) Å. The axial Cu—O bond distances are 2.365 (2) and 2.394 (2) Å. In the crystal, the complex cations and perchlorate anions are connected by numerous C—H⋯O hydrogen bonds, which leads to additional stabilization of the structure. The perchlorate anion is disordered over two sets of sites with a 0.716 (3):0.284 (3) occupancy ratio. |
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