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(2,2′-Bipyridine-κ(2) N,N′)tetrakis(dimethyl sulfoxide-κO)copper(II) bis(perchlorate)
The title compound, [Cu(C(2)H(6)OS)(4)(C(10)H(8)N(2))](ClO(4))(2), contains a Cu(II) ion with a distorted octahedral coordination environment, bonded by four O atoms of the monodentate dimethyl sulfoxide ligands and two N atoms of the bidentate chelating 2,2′-bipyridine ligand. The equatorial Cu—N...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2013
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793687/ https://www.ncbi.nlm.nih.gov/pubmed/24109274 http://dx.doi.org/10.1107/S1600536813018485 |
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author | Iskenderov, Turganbay |
author_facet | Iskenderov, Turganbay |
author_sort | Iskenderov, Turganbay |
collection | PubMed |
description | The title compound, [Cu(C(2)H(6)OS)(4)(C(10)H(8)N(2))](ClO(4))(2), contains a Cu(II) ion with a distorted octahedral coordination environment, bonded by four O atoms of the monodentate dimethyl sulfoxide ligands and two N atoms of the bidentate chelating 2,2′-bipyridine ligand. The equatorial Cu—N and Cu—O bond lengths are in the range 1.979 (2)-1.998 (3) Å. The axial Cu—O bond distances are 2.365 (2) and 2.394 (2) Å. In the crystal, the complex cations and perchlorate anions are connected by numerous C—H⋯O hydrogen bonds, which leads to additional stabilization of the structure. The perchlorate anion is disordered over two sets of sites with a 0.716 (3):0.284 (3) occupancy ratio. |
format | Online Article Text |
id | pubmed-3793687 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37936872013-10-09 (2,2′-Bipyridine-κ(2) N,N′)tetrakis(dimethyl sulfoxide-κO)copper(II) bis(perchlorate) Iskenderov, Turganbay Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(2)H(6)OS)(4)(C(10)H(8)N(2))](ClO(4))(2), contains a Cu(II) ion with a distorted octahedral coordination environment, bonded by four O atoms of the monodentate dimethyl sulfoxide ligands and two N atoms of the bidentate chelating 2,2′-bipyridine ligand. The equatorial Cu—N and Cu—O bond lengths are in the range 1.979 (2)-1.998 (3) Å. The axial Cu—O bond distances are 2.365 (2) and 2.394 (2) Å. In the crystal, the complex cations and perchlorate anions are connected by numerous C—H⋯O hydrogen bonds, which leads to additional stabilization of the structure. The perchlorate anion is disordered over two sets of sites with a 0.716 (3):0.284 (3) occupancy ratio. International Union of Crystallography 2013-07-10 /pmc/articles/PMC3793687/ /pubmed/24109274 http://dx.doi.org/10.1107/S1600536813018485 Text en © Turganbay Iskenderov 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Iskenderov, Turganbay (2,2′-Bipyridine-κ(2) N,N′)tetrakis(dimethyl sulfoxide-κO)copper(II) bis(perchlorate) |
title | (2,2′-Bipyridine-κ(2)
N,N′)tetrakis(dimethyl sulfoxide-κO)copper(II) bis(perchlorate) |
title_full | (2,2′-Bipyridine-κ(2)
N,N′)tetrakis(dimethyl sulfoxide-κO)copper(II) bis(perchlorate) |
title_fullStr | (2,2′-Bipyridine-κ(2)
N,N′)tetrakis(dimethyl sulfoxide-κO)copper(II) bis(perchlorate) |
title_full_unstemmed | (2,2′-Bipyridine-κ(2)
N,N′)tetrakis(dimethyl sulfoxide-κO)copper(II) bis(perchlorate) |
title_short | (2,2′-Bipyridine-κ(2)
N,N′)tetrakis(dimethyl sulfoxide-κO)copper(II) bis(perchlorate) |
title_sort | (2,2′-bipyridine-κ(2)
n,n′)tetrakis(dimethyl sulfoxide-κo)copper(ii) bis(perchlorate) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793687/ https://www.ncbi.nlm.nih.gov/pubmed/24109274 http://dx.doi.org/10.1107/S1600536813018485 |
work_keys_str_mv | AT iskenderovturganbay 22bipyridinek2nntetrakisdimethylsulfoxidekocopperiibisperchlorate |