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(2,2′-Bi­pyridine-κ(2) N,N′)tetra­kis­(dimethyl sulfoxide-κO)copper(II) bis­(perchlorate)

The title compound, [Cu(C(2)H(6)OS)(4)(C(10)H(8)N(2))](ClO(4))(2), contains a Cu(II) ion with a distorted octa­hedral coordination environment, bonded by four O atoms of the monodentate dimethyl sulfoxide ligands and two N atoms of the bidentate chelating 2,2′-bi­pyridine ligand. The equatorial Cu—N...

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Autor principal: Iskenderov, Turganbay
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793687/
https://www.ncbi.nlm.nih.gov/pubmed/24109274
http://dx.doi.org/10.1107/S1600536813018485
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author Iskenderov, Turganbay
author_facet Iskenderov, Turganbay
author_sort Iskenderov, Turganbay
collection PubMed
description The title compound, [Cu(C(2)H(6)OS)(4)(C(10)H(8)N(2))](ClO(4))(2), contains a Cu(II) ion with a distorted octa­hedral coordination environment, bonded by four O atoms of the monodentate dimethyl sulfoxide ligands and two N atoms of the bidentate chelating 2,2′-bi­pyridine ligand. The equatorial Cu—N and Cu—O bond lengths are in the range 1.979 (2)-1.998 (3) Å. The axial Cu—O bond distances are 2.365 (2) and 2.394 (2) Å. In the crystal, the complex cations and perchlorate anions are connected by numerous C—H⋯O hydrogen bonds, which leads to additional stabilization of the structure. The perchlorate anion is disordered over two sets of sites with a 0.716 (3):0.284 (3) occupancy ratio.
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spelling pubmed-37936872013-10-09 (2,2′-Bi­pyridine-κ(2) N,N′)tetra­kis­(dimethyl sulfoxide-κO)copper(II) bis­(perchlorate) Iskenderov, Turganbay Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(2)H(6)OS)(4)(C(10)H(8)N(2))](ClO(4))(2), contains a Cu(II) ion with a distorted octa­hedral coordination environment, bonded by four O atoms of the monodentate dimethyl sulfoxide ligands and two N atoms of the bidentate chelating 2,2′-bi­pyridine ligand. The equatorial Cu—N and Cu—O bond lengths are in the range 1.979 (2)-1.998 (3) Å. The axial Cu—O bond distances are 2.365 (2) and 2.394 (2) Å. In the crystal, the complex cations and perchlorate anions are connected by numerous C—H⋯O hydrogen bonds, which leads to additional stabilization of the structure. The perchlorate anion is disordered over two sets of sites with a 0.716 (3):0.284 (3) occupancy ratio. International Union of Crystallography 2013-07-10 /pmc/articles/PMC3793687/ /pubmed/24109274 http://dx.doi.org/10.1107/S1600536813018485 Text en © Turganbay Iskenderov 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Iskenderov, Turganbay
(2,2′-Bi­pyridine-κ(2) N,N′)tetra­kis­(dimethyl sulfoxide-κO)copper(II) bis­(perchlorate)
title (2,2′-Bi­pyridine-κ(2) N,N′)tetra­kis­(dimethyl sulfoxide-κO)copper(II) bis­(perchlorate)
title_full (2,2′-Bi­pyridine-κ(2) N,N′)tetra­kis­(dimethyl sulfoxide-κO)copper(II) bis­(perchlorate)
title_fullStr (2,2′-Bi­pyridine-κ(2) N,N′)tetra­kis­(dimethyl sulfoxide-κO)copper(II) bis­(perchlorate)
title_full_unstemmed (2,2′-Bi­pyridine-κ(2) N,N′)tetra­kis­(dimethyl sulfoxide-κO)copper(II) bis­(perchlorate)
title_short (2,2′-Bi­pyridine-κ(2) N,N′)tetra­kis­(dimethyl sulfoxide-κO)copper(II) bis­(perchlorate)
title_sort (2,2′-bi­pyridine-κ(2) n,n′)tetra­kis­(dimethyl sulfoxide-κo)copper(ii) bis­(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793687/
https://www.ncbi.nlm.nih.gov/pubmed/24109274
http://dx.doi.org/10.1107/S1600536813018485
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