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Tetra­kis(pyridine-κN)bis­(tetrafluorido­borato-κF)copper(II)

In the title complex, [Cu(BF(4))(2)(C(5)H(5)N)(2)], the Cu(II) ion is in an octa­hedral coordination environment and is surrounded by four pyridine and two tetra­fluoridoborate mol­ecules. The four pyridine mol­ecules are coordinated to the copper ion through their N atoms in the equatorial plane an...

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Detalles Bibliográficos
Autores principales: De Silva, Nirosha, Pannu, Ajay Pal Singh, Plieger, Paul G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793688/
https://www.ncbi.nlm.nih.gov/pubmed/24109275
http://dx.doi.org/10.1107/S1600536813018643
Descripción
Sumario:In the title complex, [Cu(BF(4))(2)(C(5)H(5)N)(2)], the Cu(II) ion is in an octa­hedral coordination environment and is surrounded by four pyridine and two tetra­fluoridoborate mol­ecules. The four pyridine mol­ecules are coordinated to the copper ion through their N atoms in the equatorial plane and display a right-handed screw arrangement around the Cu(II) ion. The remaining two trans positions in the octa­hedron are occupied by the BF(4) (−) anions, each coordinating weakly through an F atom. The crystal packing shows a two-dimensional sheet structure parallel to the ab plane that is formed by C—H⋯F hydrogen-bonding inter­actions.