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Tetrakis(pyridine-κN)bis(tetrafluoridoborato-κF)copper(II)
In the title complex, [Cu(BF(4))(2)(C(5)H(5)N)(2)], the Cu(II) ion is in an octahedral coordination environment and is surrounded by four pyridine and two tetrafluoridoborate molecules. The four pyridine molecules are coordinated to the copper ion through their N atoms in the equatorial plane an...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793688/ https://www.ncbi.nlm.nih.gov/pubmed/24109275 http://dx.doi.org/10.1107/S1600536813018643 |
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author | De Silva, Nirosha Pannu, Ajay Pal Singh Plieger, Paul G. |
author_facet | De Silva, Nirosha Pannu, Ajay Pal Singh Plieger, Paul G. |
author_sort | De Silva, Nirosha |
collection | PubMed |
description | In the title complex, [Cu(BF(4))(2)(C(5)H(5)N)(2)], the Cu(II) ion is in an octahedral coordination environment and is surrounded by four pyridine and two tetrafluoridoborate molecules. The four pyridine molecules are coordinated to the copper ion through their N atoms in the equatorial plane and display a right-handed screw arrangement around the Cu(II) ion. The remaining two trans positions in the octahedron are occupied by the BF(4) (−) anions, each coordinating weakly through an F atom. The crystal packing shows a two-dimensional sheet structure parallel to the ab plane that is formed by C—H⋯F hydrogen-bonding interactions. |
format | Online Article Text |
id | pubmed-3793688 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37936882013-10-09 Tetrakis(pyridine-κN)bis(tetrafluoridoborato-κF)copper(II) De Silva, Nirosha Pannu, Ajay Pal Singh Plieger, Paul G. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(BF(4))(2)(C(5)H(5)N)(2)], the Cu(II) ion is in an octahedral coordination environment and is surrounded by four pyridine and two tetrafluoridoborate molecules. The four pyridine molecules are coordinated to the copper ion through their N atoms in the equatorial plane and display a right-handed screw arrangement around the Cu(II) ion. The remaining two trans positions in the octahedron are occupied by the BF(4) (−) anions, each coordinating weakly through an F atom. The crystal packing shows a two-dimensional sheet structure parallel to the ab plane that is formed by C—H⋯F hydrogen-bonding interactions. International Union of Crystallography 2013-07-13 /pmc/articles/PMC3793688/ /pubmed/24109275 http://dx.doi.org/10.1107/S1600536813018643 Text en © De Silva et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers De Silva, Nirosha Pannu, Ajay Pal Singh Plieger, Paul G. Tetrakis(pyridine-κN)bis(tetrafluoridoborato-κF)copper(II) |
title | Tetrakis(pyridine-κN)bis(tetrafluoridoborato-κF)copper(II) |
title_full | Tetrakis(pyridine-κN)bis(tetrafluoridoborato-κF)copper(II) |
title_fullStr | Tetrakis(pyridine-κN)bis(tetrafluoridoborato-κF)copper(II) |
title_full_unstemmed | Tetrakis(pyridine-κN)bis(tetrafluoridoborato-κF)copper(II) |
title_short | Tetrakis(pyridine-κN)bis(tetrafluoridoborato-κF)copper(II) |
title_sort | tetrakis(pyridine-κn)bis(tetrafluoridoborato-κf)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793688/ https://www.ncbi.nlm.nih.gov/pubmed/24109275 http://dx.doi.org/10.1107/S1600536813018643 |
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