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Tetra­kis(pyridine-κN)bis­(tetrafluorido­borato-κF)copper(II)

In the title complex, [Cu(BF(4))(2)(C(5)H(5)N)(2)], the Cu(II) ion is in an octa­hedral coordination environment and is surrounded by four pyridine and two tetra­fluoridoborate mol­ecules. The four pyridine mol­ecules are coordinated to the copper ion through their N atoms in the equatorial plane an...

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Detalles Bibliográficos
Autores principales: De Silva, Nirosha, Pannu, Ajay Pal Singh, Plieger, Paul G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793688/
https://www.ncbi.nlm.nih.gov/pubmed/24109275
http://dx.doi.org/10.1107/S1600536813018643
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author De Silva, Nirosha
Pannu, Ajay Pal Singh
Plieger, Paul G.
author_facet De Silva, Nirosha
Pannu, Ajay Pal Singh
Plieger, Paul G.
author_sort De Silva, Nirosha
collection PubMed
description In the title complex, [Cu(BF(4))(2)(C(5)H(5)N)(2)], the Cu(II) ion is in an octa­hedral coordination environment and is surrounded by four pyridine and two tetra­fluoridoborate mol­ecules. The four pyridine mol­ecules are coordinated to the copper ion through their N atoms in the equatorial plane and display a right-handed screw arrangement around the Cu(II) ion. The remaining two trans positions in the octa­hedron are occupied by the BF(4) (−) anions, each coordinating weakly through an F atom. The crystal packing shows a two-dimensional sheet structure parallel to the ab plane that is formed by C—H⋯F hydrogen-bonding inter­actions.
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spelling pubmed-37936882013-10-09 Tetra­kis(pyridine-κN)bis­(tetrafluorido­borato-κF)copper(II) De Silva, Nirosha Pannu, Ajay Pal Singh Plieger, Paul G. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(BF(4))(2)(C(5)H(5)N)(2)], the Cu(II) ion is in an octa­hedral coordination environment and is surrounded by four pyridine and two tetra­fluoridoborate mol­ecules. The four pyridine mol­ecules are coordinated to the copper ion through their N atoms in the equatorial plane and display a right-handed screw arrangement around the Cu(II) ion. The remaining two trans positions in the octa­hedron are occupied by the BF(4) (−) anions, each coordinating weakly through an F atom. The crystal packing shows a two-dimensional sheet structure parallel to the ab plane that is formed by C—H⋯F hydrogen-bonding inter­actions. International Union of Crystallography 2013-07-13 /pmc/articles/PMC3793688/ /pubmed/24109275 http://dx.doi.org/10.1107/S1600536813018643 Text en © De Silva et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
De Silva, Nirosha
Pannu, Ajay Pal Singh
Plieger, Paul G.
Tetra­kis(pyridine-κN)bis­(tetrafluorido­borato-κF)copper(II)
title Tetra­kis(pyridine-κN)bis­(tetrafluorido­borato-κF)copper(II)
title_full Tetra­kis(pyridine-κN)bis­(tetrafluorido­borato-κF)copper(II)
title_fullStr Tetra­kis(pyridine-κN)bis­(tetrafluorido­borato-κF)copper(II)
title_full_unstemmed Tetra­kis(pyridine-κN)bis­(tetrafluorido­borato-κF)copper(II)
title_short Tetra­kis(pyridine-κN)bis­(tetrafluorido­borato-κF)copper(II)
title_sort tetra­kis(pyridine-κn)bis­(tetrafluorido­borato-κf)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793688/
https://www.ncbi.nlm.nih.gov/pubmed/24109275
http://dx.doi.org/10.1107/S1600536813018643
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