Di­aqua­bis­(pyridine-2-carboxyl­ato-κ(2) N,O)zinc di­methyl­formamide hemisolvate

In the title compound, [Zn(C(6)H(4)NO(2))(2)(H(2)O)(2)]·0.5C(3)H(7)NO, the Zn(II) ion is coordinated in a distorted octa­hedral N(2)O(4) environment by two N,O-chelating pyridine-2-carboxyl­ate ligands and two cis water mol­ecules. The chelating pyridine-2-carboxyl­ate ligands create two five-member...

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Autores principales: Croitor, Lilia, Chisca, Diana, Coropceanu, Eduard B., Fonari, Marina S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793690/
https://www.ncbi.nlm.nih.gov/pubmed/24109277
http://dx.doi.org/10.1107/S1600536813018941
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author Croitor, Lilia
Chisca, Diana
Coropceanu, Eduard B.
Fonari, Marina S.
author_facet Croitor, Lilia
Chisca, Diana
Coropceanu, Eduard B.
Fonari, Marina S.
author_sort Croitor, Lilia
collection PubMed
description In the title compound, [Zn(C(6)H(4)NO(2))(2)(H(2)O)(2)]·0.5C(3)H(7)NO, the Zn(II) ion is coordinated in a distorted octa­hedral N(2)O(4) environment by two N,O-chelating pyridine-2-carboxyl­ate ligands and two cis water mol­ecules. The chelating pyridine-2-carboxyl­ate ligands create two five-membered Zn/N/C/C/O rings, which form a dihedral angle of 86.4 (2)°. In the crystal, O—H⋯O hydrogen bonds link the complex mol­ecules into a two-dimensional network parallel to (100). The di­methyl­formamide solvent mol­ecule is disordered about a twofold rotation axis.
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spelling pubmed-37936902013-10-09 Di­aqua­bis­(pyridine-2-carboxyl­ato-κ(2) N,O)zinc di­methyl­formamide hemisolvate Croitor, Lilia Chisca, Diana Coropceanu, Eduard B. Fonari, Marina S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(6)H(4)NO(2))(2)(H(2)O)(2)]·0.5C(3)H(7)NO, the Zn(II) ion is coordinated in a distorted octa­hedral N(2)O(4) environment by two N,O-chelating pyridine-2-carboxyl­ate ligands and two cis water mol­ecules. The chelating pyridine-2-carboxyl­ate ligands create two five-membered Zn/N/C/C/O rings, which form a dihedral angle of 86.4 (2)°. In the crystal, O—H⋯O hydrogen bonds link the complex mol­ecules into a two-dimensional network parallel to (100). The di­methyl­formamide solvent mol­ecule is disordered about a twofold rotation axis. International Union of Crystallography 2013-07-13 /pmc/articles/PMC3793690/ /pubmed/24109277 http://dx.doi.org/10.1107/S1600536813018941 Text en © Croitor et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Croitor, Lilia
Chisca, Diana
Coropceanu, Eduard B.
Fonari, Marina S.
Di­aqua­bis­(pyridine-2-carboxyl­ato-κ(2) N,O)zinc di­methyl­formamide hemisolvate
title Di­aqua­bis­(pyridine-2-carboxyl­ato-κ(2) N,O)zinc di­methyl­formamide hemisolvate
title_full Di­aqua­bis­(pyridine-2-carboxyl­ato-κ(2) N,O)zinc di­methyl­formamide hemisolvate
title_fullStr Di­aqua­bis­(pyridine-2-carboxyl­ato-κ(2) N,O)zinc di­methyl­formamide hemisolvate
title_full_unstemmed Di­aqua­bis­(pyridine-2-carboxyl­ato-κ(2) N,O)zinc di­methyl­formamide hemisolvate
title_short Di­aqua­bis­(pyridine-2-carboxyl­ato-κ(2) N,O)zinc di­methyl­formamide hemisolvate
title_sort di­aqua­bis­(pyridine-2-carboxyl­ato-κ(2) n,o)zinc di­methyl­formamide hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793690/
https://www.ncbi.nlm.nih.gov/pubmed/24109277
http://dx.doi.org/10.1107/S1600536813018941
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