Bis[μ-3,5-bis­(pyridin-2-yl)pyrazolato]bis­[(hexa­fluoro­phosphato)copper(II)]

The title dinuclear complex mol­ecule, [Cu(2)(C(13)H(9)N(4))(2)(PF(6))(2)], lies about an inversion center. The Cu(II) atom shows a square-pyramidal coordination geometry with the basal plane formed by four N atoms of the two bis-chelating 3,5-bis­(pyridin-2-yl)pyrazolate ions and with one F atom of...

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Autores principales: Mishima, Akio, Katsuta, Nagisa, Furusyou, Midori, Fuyuhiro, Akira, Kawata, Satoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793691/
https://www.ncbi.nlm.nih.gov/pubmed/24109278
http://dx.doi.org/10.1107/S1600536813018813
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author Mishima, Akio
Katsuta, Nagisa
Furusyou, Midori
Fuyuhiro, Akira
Kawata, Satoshi
author_facet Mishima, Akio
Katsuta, Nagisa
Furusyou, Midori
Fuyuhiro, Akira
Kawata, Satoshi
author_sort Mishima, Akio
collection PubMed
description The title dinuclear complex mol­ecule, [Cu(2)(C(13)H(9)N(4))(2)(PF(6))(2)], lies about an inversion center. The Cu(II) atom shows a square-pyramidal coordination geometry with the basal plane formed by four N atoms of the two bis-chelating 3,5-bis­(pyridin-2-yl)pyrazolate ions and with one F atom of the hexa­fluoro­phosphate ion in the apical position. Mol­ecules are stacked in a column along the a axis through C—H⋯F hydrogen bonds. The columns are further linked by other C—H⋯F hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-37936912013-10-09 Bis[μ-3,5-bis­(pyridin-2-yl)pyrazolato]bis­[(hexa­fluoro­phosphato)copper(II)] Mishima, Akio Katsuta, Nagisa Furusyou, Midori Fuyuhiro, Akira Kawata, Satoshi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title dinuclear complex mol­ecule, [Cu(2)(C(13)H(9)N(4))(2)(PF(6))(2)], lies about an inversion center. The Cu(II) atom shows a square-pyramidal coordination geometry with the basal plane formed by four N atoms of the two bis-chelating 3,5-bis­(pyridin-2-yl)pyrazolate ions and with one F atom of the hexa­fluoro­phosphate ion in the apical position. Mol­ecules are stacked in a column along the a axis through C—H⋯F hydrogen bonds. The columns are further linked by other C—H⋯F hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2013-07-13 /pmc/articles/PMC3793691/ /pubmed/24109278 http://dx.doi.org/10.1107/S1600536813018813 Text en © Mishima et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mishima, Akio
Katsuta, Nagisa
Furusyou, Midori
Fuyuhiro, Akira
Kawata, Satoshi
Bis[μ-3,5-bis­(pyridin-2-yl)pyrazolato]bis­[(hexa­fluoro­phosphato)copper(II)]
title Bis[μ-3,5-bis­(pyridin-2-yl)pyrazolato]bis­[(hexa­fluoro­phosphato)copper(II)]
title_full Bis[μ-3,5-bis­(pyridin-2-yl)pyrazolato]bis­[(hexa­fluoro­phosphato)copper(II)]
title_fullStr Bis[μ-3,5-bis­(pyridin-2-yl)pyrazolato]bis­[(hexa­fluoro­phosphato)copper(II)]
title_full_unstemmed Bis[μ-3,5-bis­(pyridin-2-yl)pyrazolato]bis­[(hexa­fluoro­phosphato)copper(II)]
title_short Bis[μ-3,5-bis­(pyridin-2-yl)pyrazolato]bis­[(hexa­fluoro­phosphato)copper(II)]
title_sort bis[μ-3,5-bis­(pyridin-2-yl)pyrazolato]bis­[(hexa­fluoro­phosphato)copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793691/
https://www.ncbi.nlm.nih.gov/pubmed/24109278
http://dx.doi.org/10.1107/S1600536813018813
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