Bis{N-benzyl-N-[2-(thio­phen-2-yl)eth­yl]di­thio­carbamato-κ(2) S,S′}lead(II)

The mol­ecule of the title compound, [Pb(C(14)H(14)NS(3))(2)], is located on a twofold rotation axis. The di­thio­carbamate anion S,S′-chelates to the Pb(II) atom, which shows a Ψ-trigonal–bipyramidal coordination. The thio­phene ring is disordered over two positions, the major component having 71.3...

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Detalles Bibliográficos
Autores principales: Sathiyaraj, E., Thirumaran, S., Sridhar, B., Selvanayagam, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793692/
https://www.ncbi.nlm.nih.gov/pubmed/24109279
http://dx.doi.org/10.1107/S1600536813019259
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author Sathiyaraj, E.
Thirumaran, S.
Sridhar, B.
Selvanayagam, S.
author_facet Sathiyaraj, E.
Thirumaran, S.
Sridhar, B.
Selvanayagam, S.
author_sort Sathiyaraj, E.
collection PubMed
description The mol­ecule of the title compound, [Pb(C(14)H(14)NS(3))(2)], is located on a twofold rotation axis. The di­thio­carbamate anion S,S′-chelates to the Pb(II) atom, which shows a Ψ-trigonal–bipyramidal coordination. The thio­phene ring is disordered over two positions, the major component having 71.3 (7)% occupancy. The mol­ecular conformation is stabilized by intra­molecular C—H⋯S inter­actions.
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spelling pubmed-37936922013-10-09 Bis{N-benzyl-N-[2-(thio­phen-2-yl)eth­yl]di­thio­carbamato-κ(2) S,S′}lead(II) Sathiyaraj, E. Thirumaran, S. Sridhar, B. Selvanayagam, S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mol­ecule of the title compound, [Pb(C(14)H(14)NS(3))(2)], is located on a twofold rotation axis. The di­thio­carbamate anion S,S′-chelates to the Pb(II) atom, which shows a Ψ-trigonal–bipyramidal coordination. The thio­phene ring is disordered over two positions, the major component having 71.3 (7)% occupancy. The mol­ecular conformation is stabilized by intra­molecular C—H⋯S inter­actions. International Union of Crystallography 2013-07-17 /pmc/articles/PMC3793692/ /pubmed/24109279 http://dx.doi.org/10.1107/S1600536813019259 Text en © Sathiyaraj et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sathiyaraj, E.
Thirumaran, S.
Sridhar, B.
Selvanayagam, S.
Bis{N-benzyl-N-[2-(thio­phen-2-yl)eth­yl]di­thio­carbamato-κ(2) S,S′}lead(II)
title Bis{N-benzyl-N-[2-(thio­phen-2-yl)eth­yl]di­thio­carbamato-κ(2) S,S′}lead(II)
title_full Bis{N-benzyl-N-[2-(thio­phen-2-yl)eth­yl]di­thio­carbamato-κ(2) S,S′}lead(II)
title_fullStr Bis{N-benzyl-N-[2-(thio­phen-2-yl)eth­yl]di­thio­carbamato-κ(2) S,S′}lead(II)
title_full_unstemmed Bis{N-benzyl-N-[2-(thio­phen-2-yl)eth­yl]di­thio­carbamato-κ(2) S,S′}lead(II)
title_short Bis{N-benzyl-N-[2-(thio­phen-2-yl)eth­yl]di­thio­carbamato-κ(2) S,S′}lead(II)
title_sort bis{n-benzyl-n-[2-(thio­phen-2-yl)eth­yl]di­thio­carbamato-κ(2) s,s′}lead(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793692/
https://www.ncbi.nlm.nih.gov/pubmed/24109279
http://dx.doi.org/10.1107/S1600536813019259
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AT sridharb bisnbenzyln2thiophen2ylethyldithiocarbamatok2ssleadii
AT selvanayagams bisnbenzyln2thiophen2ylethyldithiocarbamatok2ssleadii

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