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Aquabis(3-chlorobenzoato-κO)bis(N,N-diethylnicotinamide-κN)copper(II)
The title compound, [Cu(C(7)H(4)ClO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)], has twofold symmetry with the Cu(II) cation and the O atom of the coordinating water molecule located on the axis. The Cu(II) cation is coordinated by two carboxylate O atoms of chlorobenzoate (CB) anions, two N atoms of N,N-...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793693/ https://www.ncbi.nlm.nih.gov/pubmed/24109280 http://dx.doi.org/10.1107/S1600536813018989 |
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author | Bozkurt, Nihat Tunç, Tuncay Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_facet | Bozkurt, Nihat Tunç, Tuncay Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_sort | Bozkurt, Nihat |
collection | PubMed |
description | The title compound, [Cu(C(7)H(4)ClO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)], has twofold symmetry with the Cu(II) cation and the O atom of the coordinating water molecule located on the axis. The Cu(II) cation is coordinated by two carboxylate O atoms of chlorobenzoate (CB) anions, two N atoms of N,N-diethylnicotinamide (DENA) ligands and one water molecule in a distorted N(2)O(3) square-pyramidal geometry. The benzene and pyridine rings are oriented at a dihedral angle of 82.51 (6)°. In the anionic ligand, the carboxylate group is twisted away from the attached benzene ring by 12.85 (11)°. In the crystal, O—H⋯O hydrogen bonds between the coordinating water molecule and the carboxyl group link the complex molecules into supramolecular chains running along the c-axis direction. |
format | Online Article Text |
id | pubmed-3793693 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37936932013-10-09 Aquabis(3-chlorobenzoato-κO)bis(N,N-diethylnicotinamide-κN)copper(II) Bozkurt, Nihat Tunç, Tuncay Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(7)H(4)ClO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)], has twofold symmetry with the Cu(II) cation and the O atom of the coordinating water molecule located on the axis. The Cu(II) cation is coordinated by two carboxylate O atoms of chlorobenzoate (CB) anions, two N atoms of N,N-diethylnicotinamide (DENA) ligands and one water molecule in a distorted N(2)O(3) square-pyramidal geometry. The benzene and pyridine rings are oriented at a dihedral angle of 82.51 (6)°. In the anionic ligand, the carboxylate group is twisted away from the attached benzene ring by 12.85 (11)°. In the crystal, O—H⋯O hydrogen bonds between the coordinating water molecule and the carboxyl group link the complex molecules into supramolecular chains running along the c-axis direction. International Union of Crystallography 2013-07-17 /pmc/articles/PMC3793693/ /pubmed/24109280 http://dx.doi.org/10.1107/S1600536813018989 Text en © Bozkurt et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bozkurt, Nihat Tunç, Tuncay Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Aquabis(3-chlorobenzoato-κO)bis(N,N-diethylnicotinamide-κN)copper(II) |
title | Aquabis(3-chlorobenzoato-κO)bis(N,N-diethylnicotinamide-κN)copper(II) |
title_full | Aquabis(3-chlorobenzoato-κO)bis(N,N-diethylnicotinamide-κN)copper(II) |
title_fullStr | Aquabis(3-chlorobenzoato-κO)bis(N,N-diethylnicotinamide-κN)copper(II) |
title_full_unstemmed | Aquabis(3-chlorobenzoato-κO)bis(N,N-diethylnicotinamide-κN)copper(II) |
title_short | Aquabis(3-chlorobenzoato-κO)bis(N,N-diethylnicotinamide-κN)copper(II) |
title_sort | aquabis(3-chlorobenzoato-κo)bis(n,n-diethylnicotinamide-κn)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793693/ https://www.ncbi.nlm.nih.gov/pubmed/24109280 http://dx.doi.org/10.1107/S1600536813018989 |
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