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Aqua­bis­(3-chloro­benzoato-κO)bis­(N,N-di­ethyl­nicotinamide-κN)copper(II)

The title compound, [Cu(C(7)H(4)ClO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)], has twofold symmetry with the Cu(II) cation and the O atom of the coordinating water mol­ecule located on the axis. The Cu(II) cation is coordinated by two carboxyl­ate O atoms of chloro­benzoate (CB) anions, two N atoms of N,N-...

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Autores principales: Bozkurt, Nihat, Tunç, Tuncay, Çaylak Delibaş, Nagihan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793693/
https://www.ncbi.nlm.nih.gov/pubmed/24109280
http://dx.doi.org/10.1107/S1600536813018989
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author Bozkurt, Nihat
Tunç, Tuncay
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_facet Bozkurt, Nihat
Tunç, Tuncay
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_sort Bozkurt, Nihat
collection PubMed
description The title compound, [Cu(C(7)H(4)ClO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)], has twofold symmetry with the Cu(II) cation and the O atom of the coordinating water mol­ecule located on the axis. The Cu(II) cation is coordinated by two carboxyl­ate O atoms of chloro­benzoate (CB) anions, two N atoms of N,N-di­ethyl­nicotinamide (DENA) ligands and one water mol­ecule in a distorted N(2)O(3) square-pyramidal geometry. The benzene and pyridine rings are oriented at a dihedral angle of 82.51 (6)°. In the anionic ligand, the carboxyl­ate group is twisted away from the attached benzene ring by 12.85 (11)°. In the crystal, O—H⋯O hydrogen bonds between the coordinating water mol­ecule and the carboxyl group link the complex mol­ecules into supra­molecular chains running along the c-axis direction.
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spelling pubmed-37936932013-10-09 Aqua­bis­(3-chloro­benzoato-κO)bis­(N,N-di­ethyl­nicotinamide-κN)copper(II) Bozkurt, Nihat Tunç, Tuncay Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(7)H(4)ClO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)], has twofold symmetry with the Cu(II) cation and the O atom of the coordinating water mol­ecule located on the axis. The Cu(II) cation is coordinated by two carboxyl­ate O atoms of chloro­benzoate (CB) anions, two N atoms of N,N-di­ethyl­nicotinamide (DENA) ligands and one water mol­ecule in a distorted N(2)O(3) square-pyramidal geometry. The benzene and pyridine rings are oriented at a dihedral angle of 82.51 (6)°. In the anionic ligand, the carboxyl­ate group is twisted away from the attached benzene ring by 12.85 (11)°. In the crystal, O—H⋯O hydrogen bonds between the coordinating water mol­ecule and the carboxyl group link the complex mol­ecules into supra­molecular chains running along the c-axis direction. International Union of Crystallography 2013-07-17 /pmc/articles/PMC3793693/ /pubmed/24109280 http://dx.doi.org/10.1107/S1600536813018989 Text en © Bozkurt et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bozkurt, Nihat
Tunç, Tuncay
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
Aqua­bis­(3-chloro­benzoato-κO)bis­(N,N-di­ethyl­nicotinamide-κN)copper(II)
title Aqua­bis­(3-chloro­benzoato-κO)bis­(N,N-di­ethyl­nicotinamide-κN)copper(II)
title_full Aqua­bis­(3-chloro­benzoato-κO)bis­(N,N-di­ethyl­nicotinamide-κN)copper(II)
title_fullStr Aqua­bis­(3-chloro­benzoato-κO)bis­(N,N-di­ethyl­nicotinamide-κN)copper(II)
title_full_unstemmed Aqua­bis­(3-chloro­benzoato-κO)bis­(N,N-di­ethyl­nicotinamide-κN)copper(II)
title_short Aqua­bis­(3-chloro­benzoato-κO)bis­(N,N-di­ethyl­nicotinamide-κN)copper(II)
title_sort aqua­bis­(3-chloro­benzoato-κo)bis­(n,n-di­ethyl­nicotinamide-κn)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793693/
https://www.ncbi.nlm.nih.gov/pubmed/24109280
http://dx.doi.org/10.1107/S1600536813018989
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