Poly[[μ-bis­(4-nitro­phen­yl) phosphato-κ(2) O,O′]sodium]

The title compound, [Na(C(12)H(8)N(2)O(8)P)], consists of one Na(+) cation and one bis­(p-nitro­phen­yl)phosphate anion with a considerable distortion of the phosphate tetra­hedron due to the presence of two P—O ester bonds. The anion bridges five Na(+) cations whereby each cation is chelated by the...

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Detalles Bibliográficos
Autores principales: Gerus, Aleksandra, Lis, Tadeusz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793696/
https://www.ncbi.nlm.nih.gov/pubmed/24109283
http://dx.doi.org/10.1107/S1600536813019260
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author Gerus, Aleksandra
Lis, Tadeusz
author_facet Gerus, Aleksandra
Lis, Tadeusz
author_sort Gerus, Aleksandra
collection PubMed
description The title compound, [Na(C(12)H(8)N(2)O(8)P)], consists of one Na(+) cation and one bis­(p-nitro­phen­yl)phosphate anion with a considerable distortion of the phosphate tetra­hedron due to the presence of two P—O ester bonds. The anion bridges five Na(+) cations whereby each cation is chelated by the nitro O atoms of one anion and bonded via a nitro O atom and phosphate O atoms to four other anions. This bridging arrangement leads to the formation of double layers parallel to (001). Adjacent layers are linked through weak C—H⋯O hydrogen bonds.
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spelling pubmed-37936962013-10-09 Poly[[μ-bis­(4-nitro­phen­yl) phosphato-κ(2) O,O′]sodium] Gerus, Aleksandra Lis, Tadeusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Na(C(12)H(8)N(2)O(8)P)], consists of one Na(+) cation and one bis­(p-nitro­phen­yl)phosphate anion with a considerable distortion of the phosphate tetra­hedron due to the presence of two P—O ester bonds. The anion bridges five Na(+) cations whereby each cation is chelated by the nitro O atoms of one anion and bonded via a nitro O atom and phosphate O atoms to four other anions. This bridging arrangement leads to the formation of double layers parallel to (001). Adjacent layers are linked through weak C—H⋯O hydrogen bonds. International Union of Crystallography 2013-07-20 /pmc/articles/PMC3793696/ /pubmed/24109283 http://dx.doi.org/10.1107/S1600536813019260 Text en © Gerus and Lis 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gerus, Aleksandra
Lis, Tadeusz
Poly[[μ-bis­(4-nitro­phen­yl) phosphato-κ(2) O,O′]sodium]
title Poly[[μ-bis­(4-nitro­phen­yl) phosphato-κ(2) O,O′]sodium]
title_full Poly[[μ-bis­(4-nitro­phen­yl) phosphato-κ(2) O,O′]sodium]
title_fullStr Poly[[μ-bis­(4-nitro­phen­yl) phosphato-κ(2) O,O′]sodium]
title_full_unstemmed Poly[[μ-bis­(4-nitro­phen­yl) phosphato-κ(2) O,O′]sodium]
title_short Poly[[μ-bis­(4-nitro­phen­yl) phosphato-κ(2) O,O′]sodium]
title_sort poly[[μ-bis­(4-nitro­phen­yl) phosphato-κ(2) o,o′]sodium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793696/
https://www.ncbi.nlm.nih.gov/pubmed/24109283
http://dx.doi.org/10.1107/S1600536813019260
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AT listadeusz polymbis4nitrophenylphosphatok2oosodium

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