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catena-Poly[[aquabis(3-chlorobenzoato-κ(2) O,O′)cadmium]-μ-N,N-diethylnicotinamide-κ(2) N (1):O]
In the crystal of the title Cd(II) polymeric complex, [Cd(C(7)H(4)ClO(2))(2)(C(10)H(14)N(2)O)(H(2)O)](n), the Cd(II) cation is chelated by two chlorobenzoate anions and coordinated by two N,N-diethylnicotinamide (DENA) ligands and one water molecule in a distorted NO(6) pentagonal–bipyramidal...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793697/ https://www.ncbi.nlm.nih.gov/pubmed/24109284 http://dx.doi.org/10.1107/S160053681301965X |
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author | Bozkurt, Nihat Tunç, Tuncay Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_facet | Bozkurt, Nihat Tunç, Tuncay Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_sort | Bozkurt, Nihat |
collection | PubMed |
description | In the crystal of the title Cd(II) polymeric complex, [Cd(C(7)H(4)ClO(2))(2)(C(10)H(14)N(2)O)(H(2)O)](n), the Cd(II) cation is chelated by two chlorobenzoate anions and coordinated by two N,N-diethylnicotinamide (DENA) ligands and one water molecule in a distorted NO(6) pentagonal–bipyramidal geometry. The Cd(II) cations are bridged by the pyridine N atom and carbonyl O atom of the DENA ligand to form a polymeric chain running along the b axis. Intermolecular O—H⋯O hydrogen bonds between coordinating water molecules and carboxylate groups link adjacent chains into layers parallel to the bc plane. π–π contacts between benzene rings [shortest centroid–centroid distance = 3.912 (2) Å] further stabilizes the crystal structure. In the molecule, weak C—H⋯O hydrogen bonds occur between the pyridine ring and carboxylate groups; the dihedral angles between the carboxylate groups and adjacent benzene rings are 4.6 (3) and 12.8 (3)°, while the benzene rings are oriented at a dihedral angle of 1.89 (13)°. |
format | Online Article Text |
id | pubmed-3793697 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37936972013-10-09 catena-Poly[[aquabis(3-chlorobenzoato-κ(2) O,O′)cadmium]-μ-N,N-diethylnicotinamide-κ(2) N (1):O] Bozkurt, Nihat Tunç, Tuncay Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal of the title Cd(II) polymeric complex, [Cd(C(7)H(4)ClO(2))(2)(C(10)H(14)N(2)O)(H(2)O)](n), the Cd(II) cation is chelated by two chlorobenzoate anions and coordinated by two N,N-diethylnicotinamide (DENA) ligands and one water molecule in a distorted NO(6) pentagonal–bipyramidal geometry. The Cd(II) cations are bridged by the pyridine N atom and carbonyl O atom of the DENA ligand to form a polymeric chain running along the b axis. Intermolecular O—H⋯O hydrogen bonds between coordinating water molecules and carboxylate groups link adjacent chains into layers parallel to the bc plane. π–π contacts between benzene rings [shortest centroid–centroid distance = 3.912 (2) Å] further stabilizes the crystal structure. In the molecule, weak C—H⋯O hydrogen bonds occur between the pyridine ring and carboxylate groups; the dihedral angles between the carboxylate groups and adjacent benzene rings are 4.6 (3) and 12.8 (3)°, while the benzene rings are oriented at a dihedral angle of 1.89 (13)°. International Union of Crystallography 2013-07-20 /pmc/articles/PMC3793697/ /pubmed/24109284 http://dx.doi.org/10.1107/S160053681301965X Text en © Bozkurt et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bozkurt, Nihat Tunç, Tuncay Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer catena-Poly[[aquabis(3-chlorobenzoato-κ(2) O,O′)cadmium]-μ-N,N-diethylnicotinamide-κ(2) N (1):O] |
title |
catena-Poly[[aquabis(3-chlorobenzoato-κ(2)
O,O′)cadmium]-μ-N,N-diethylnicotinamide-κ(2)
N
(1):O] |
title_full |
catena-Poly[[aquabis(3-chlorobenzoato-κ(2)
O,O′)cadmium]-μ-N,N-diethylnicotinamide-κ(2)
N
(1):O] |
title_fullStr |
catena-Poly[[aquabis(3-chlorobenzoato-κ(2)
O,O′)cadmium]-μ-N,N-diethylnicotinamide-κ(2)
N
(1):O] |
title_full_unstemmed |
catena-Poly[[aquabis(3-chlorobenzoato-κ(2)
O,O′)cadmium]-μ-N,N-diethylnicotinamide-κ(2)
N
(1):O] |
title_short |
catena-Poly[[aquabis(3-chlorobenzoato-κ(2)
O,O′)cadmium]-μ-N,N-diethylnicotinamide-κ(2)
N
(1):O] |
title_sort | catena-poly[[aquabis(3-chlorobenzoato-κ(2)
o,o′)cadmium]-μ-n,n-diethylnicotinamide-κ(2)
n
(1):o] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793697/ https://www.ncbi.nlm.nih.gov/pubmed/24109284 http://dx.doi.org/10.1107/S160053681301965X |
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