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catena-Poly[[aqua­bis­(3-chloro­benzoato-κ(2) O,O′)cadmium]-μ-N,N-di­ethyl­nico­tin­amide-κ(2) N (1):O]

In the crystal of the title Cd(II) polymeric complex, [Cd(C(7)H(4)ClO(2))(2)(C(10)H(14)N(2)O)(H(2)O)](n), the Cd(II) cation is chelated by two chloro­benzoate anions and coordinated by two N,N-di­­ethyl­nicotinamide (DENA) ligands and one water mol­ecule in a distorted NO(6) penta­gonal–bipyramidal...

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Autores principales: Bozkurt, Nihat, Tunç, Tuncay, Çaylak Delibaş, Nagihan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793697/
https://www.ncbi.nlm.nih.gov/pubmed/24109284
http://dx.doi.org/10.1107/S160053681301965X
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author Bozkurt, Nihat
Tunç, Tuncay
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_facet Bozkurt, Nihat
Tunç, Tuncay
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_sort Bozkurt, Nihat
collection PubMed
description In the crystal of the title Cd(II) polymeric complex, [Cd(C(7)H(4)ClO(2))(2)(C(10)H(14)N(2)O)(H(2)O)](n), the Cd(II) cation is chelated by two chloro­benzoate anions and coordinated by two N,N-di­­ethyl­nicotinamide (DENA) ligands and one water mol­ecule in a distorted NO(6) penta­gonal–bipyramidal geometry. The Cd(II) cations are bridged by the pyridine N atom and carbonyl O atom of the DENA ligand to form a polymeric chain running along the b axis. Inter­molecular O—H⋯O hydrogen bonds between coordinating water mol­ecules and carboxyl­ate groups link adjacent chains into layers parallel to the bc plane. π–π contacts between benzene rings [shortest centroid–centroid distance = 3.912 (2) Å] further stabilizes the crystal structure. In the mol­ecule, weak C—H⋯O hydrogen bonds occur between the pyridine ring and carboxyl­ate groups; the dihedral angles between the carboxyl­ate groups and adjacent benzene rings are 4.6 (3) and 12.8 (3)°, while the benzene rings are oriented at a dihedral angle of 1.89 (13)°.
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spelling pubmed-37936972013-10-09 catena-Poly[[aqua­bis­(3-chloro­benzoato-κ(2) O,O′)cadmium]-μ-N,N-di­ethyl­nico­tin­amide-κ(2) N (1):O] Bozkurt, Nihat Tunç, Tuncay Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal of the title Cd(II) polymeric complex, [Cd(C(7)H(4)ClO(2))(2)(C(10)H(14)N(2)O)(H(2)O)](n), the Cd(II) cation is chelated by two chloro­benzoate anions and coordinated by two N,N-di­­ethyl­nicotinamide (DENA) ligands and one water mol­ecule in a distorted NO(6) penta­gonal–bipyramidal geometry. The Cd(II) cations are bridged by the pyridine N atom and carbonyl O atom of the DENA ligand to form a polymeric chain running along the b axis. Inter­molecular O—H⋯O hydrogen bonds between coordinating water mol­ecules and carboxyl­ate groups link adjacent chains into layers parallel to the bc plane. π–π contacts between benzene rings [shortest centroid–centroid distance = 3.912 (2) Å] further stabilizes the crystal structure. In the mol­ecule, weak C—H⋯O hydrogen bonds occur between the pyridine ring and carboxyl­ate groups; the dihedral angles between the carboxyl­ate groups and adjacent benzene rings are 4.6 (3) and 12.8 (3)°, while the benzene rings are oriented at a dihedral angle of 1.89 (13)°. International Union of Crystallography 2013-07-20 /pmc/articles/PMC3793697/ /pubmed/24109284 http://dx.doi.org/10.1107/S160053681301965X Text en © Bozkurt et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bozkurt, Nihat
Tunç, Tuncay
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
catena-Poly[[aqua­bis­(3-chloro­benzoato-κ(2) O,O′)cadmium]-μ-N,N-di­ethyl­nico­tin­amide-κ(2) N (1):O]
title catena-Poly[[aqua­bis­(3-chloro­benzoato-κ(2) O,O′)cadmium]-μ-N,N-di­ethyl­nico­tin­amide-κ(2) N (1):O]
title_full catena-Poly[[aqua­bis­(3-chloro­benzoato-κ(2) O,O′)cadmium]-μ-N,N-di­ethyl­nico­tin­amide-κ(2) N (1):O]
title_fullStr catena-Poly[[aqua­bis­(3-chloro­benzoato-κ(2) O,O′)cadmium]-μ-N,N-di­ethyl­nico­tin­amide-κ(2) N (1):O]
title_full_unstemmed catena-Poly[[aqua­bis­(3-chloro­benzoato-κ(2) O,O′)cadmium]-μ-N,N-di­ethyl­nico­tin­amide-κ(2) N (1):O]
title_short catena-Poly[[aqua­bis­(3-chloro­benzoato-κ(2) O,O′)cadmium]-μ-N,N-di­ethyl­nico­tin­amide-κ(2) N (1):O]
title_sort catena-poly[[aqua­bis­(3-chloro­benzoato-κ(2) o,o′)cadmium]-μ-n,n-di­ethyl­nico­tin­amide-κ(2) n (1):o]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793697/
https://www.ncbi.nlm.nih.gov/pubmed/24109284
http://dx.doi.org/10.1107/S160053681301965X
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