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[5,10,15,20-Tetrakis(4-methoxyphenyl)porphyrinato]zinc dichloromethane disolvate
In the title compound, [Zn(C(48)H(36)N(4)O(4))]·2CH(2)Cl(2), the Zn(II) ion lies on an inversion center and is coordinated in an almost ideal square-planar geometry. The asymmetric unit also contains one dichloromethane solvent molecule. The unique methoxy-substituted benzene rings form dihedral...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793700/ https://www.ncbi.nlm.nih.gov/pubmed/24109287 http://dx.doi.org/10.1107/S1600536813019338 |
Sumario: | In the title compound, [Zn(C(48)H(36)N(4)O(4))]·2CH(2)Cl(2), the Zn(II) ion lies on an inversion center and is coordinated in an almost ideal square-planar geometry. The asymmetric unit also contains one dichloromethane solvent molecule. The unique methoxy-substituted benzene rings form dihedral angles of 59.38 (6) and 66.77 (6)° with the mean plane (r.m.s. deviation of fitted atoms = 0.0282 Å) of the atoms in the porphyrin core. The packing is characterized by close contacts between the Zn(II) ion and two symmetry-related molecules through the O atoms of a methoxyphenyl group [Zn⋯O = 2.694 (2) Å], forming a two-dimensional network parallel to (100). |
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