[5,10,15,20-Tetra­kis(4-meth­oxy­phen­yl)porphyrinato]zinc di­chloro­methane disolvate

In the title compound, [Zn(C(48)H(36)N(4)O(4))]·2CH(2)Cl(2), the Zn(II) ion lies on an inversion center and is coordinated in an almost ideal square-planar geometry. The asymmetric unit also contains one di­chloro­methane solvent mol­ecule. The unique meth­oxy-substituted benzene rings form dihedral...

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Detalles Bibliográficos
Autores principales: McGill, Sean, Nesterov, Vladimir N., Gould, Stephanie L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793700/
https://www.ncbi.nlm.nih.gov/pubmed/24109287
http://dx.doi.org/10.1107/S1600536813019338
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author McGill, Sean
Nesterov, Vladimir N.
Gould, Stephanie L.
author_facet McGill, Sean
Nesterov, Vladimir N.
Gould, Stephanie L.
author_sort McGill, Sean
collection PubMed
description In the title compound, [Zn(C(48)H(36)N(4)O(4))]·2CH(2)Cl(2), the Zn(II) ion lies on an inversion center and is coordinated in an almost ideal square-planar geometry. The asymmetric unit also contains one di­chloro­methane solvent mol­ecule. The unique meth­oxy-substituted benzene rings form dihedral angles of 59.38 (6) and 66.77 (6)° with the mean plane (r.m.s. deviation of fitted atoms = 0.0282 Å) of the atoms in the porphyrin core. The packing is characterized by close contacts between the Zn(II) ion and two symmetry-related mol­ecules through the O atoms of a meth­oxy­phenyl group [Zn⋯O = 2.694 (2) Å], forming a two-dimensional network parallel to (100).
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spelling pubmed-37937002013-10-09 [5,10,15,20-Tetra­kis(4-meth­oxy­phen­yl)porphyrinato]zinc di­chloro­methane disolvate McGill, Sean Nesterov, Vladimir N. Gould, Stephanie L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(48)H(36)N(4)O(4))]·2CH(2)Cl(2), the Zn(II) ion lies on an inversion center and is coordinated in an almost ideal square-planar geometry. The asymmetric unit also contains one di­chloro­methane solvent mol­ecule. The unique meth­oxy-substituted benzene rings form dihedral angles of 59.38 (6) and 66.77 (6)° with the mean plane (r.m.s. deviation of fitted atoms = 0.0282 Å) of the atoms in the porphyrin core. The packing is characterized by close contacts between the Zn(II) ion and two symmetry-related mol­ecules through the O atoms of a meth­oxy­phenyl group [Zn⋯O = 2.694 (2) Å], forming a two-dimensional network parallel to (100). International Union of Crystallography 2013-07-24 /pmc/articles/PMC3793700/ /pubmed/24109287 http://dx.doi.org/10.1107/S1600536813019338 Text en © McGill et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
McGill, Sean
Nesterov, Vladimir N.
Gould, Stephanie L.
[5,10,15,20-Tetra­kis(4-meth­oxy­phen­yl)porphyrinato]zinc di­chloro­methane disolvate
title [5,10,15,20-Tetra­kis(4-meth­oxy­phen­yl)porphyrinato]zinc di­chloro­methane disolvate
title_full [5,10,15,20-Tetra­kis(4-meth­oxy­phen­yl)porphyrinato]zinc di­chloro­methane disolvate
title_fullStr [5,10,15,20-Tetra­kis(4-meth­oxy­phen­yl)porphyrinato]zinc di­chloro­methane disolvate
title_full_unstemmed [5,10,15,20-Tetra­kis(4-meth­oxy­phen­yl)porphyrinato]zinc di­chloro­methane disolvate
title_short [5,10,15,20-Tetra­kis(4-meth­oxy­phen­yl)porphyrinato]zinc di­chloro­methane disolvate
title_sort [5,10,15,20-tetra­kis(4-meth­oxy­phen­yl)porphyrinato]zinc di­chloro­methane disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793700/
https://www.ncbi.nlm.nih.gov/pubmed/24109287
http://dx.doi.org/10.1107/S1600536813019338
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