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trans-Bis(μ-benzene­thiol­ato-κ(2) S:S)bis[chlorido­(tri­phenyl­phosphane-κP)palladium(II)] chloro­form disolvate

The title compound, [Pd(2)Cl(2)(C(6)H(5)S)(2)(C(18)H(15)P)(2)]·2CHCl(3), contains a centrosymmetric dinuclear palladium complex with the Pd(II) cation in a slightly distorted square-planar coordination environment. The Pd(II) cations are bridged by the S atoms of two benzene­thiol­ate ligands with d...

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Detalles Bibliográficos
Autores principales: Avila-Sorrosa, Alcives, Reyes-Arellano, Alicia, Germán-Acacio, Juan Manuel, Reyes-Martínez, Reyna, Morales-Morales, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793701/
https://www.ncbi.nlm.nih.gov/pubmed/24109288
http://dx.doi.org/10.1107/S1600536813019806
Descripción
Sumario:The title compound, [Pd(2)Cl(2)(C(6)H(5)S)(2)(C(18)H(15)P)(2)]·2CHCl(3), contains a centrosymmetric dinuclear palladium complex with the Pd(II) cation in a slightly distorted square-planar coordination environment. The Pd(II) cations are bridged by the S atoms of two benzene­thiol­ate ligands with different Pd—S distances [2.2970 (11) and 2.3676 (11) Å]. The coordination of the metal atom is completed by a chloride anion [2.3383 (11) Å] and a tri­phenyl­phosphane ligand [2.2787 (11) Å]. Weak C—H⋯Cl inter­actions are present between complex mol­ecules and the CHCl(3) solvent mol­ecule. The latter is disordered over two positions in a 0.792 (8):0.208 (8) ratio. The crystal under investigation was found to be twinned by nonmerohedry, with a fraction of 73.4 (1)% for the major twin component.