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trans-Bis(μ-benzenethiolato-κ(2) S:S)bis[chlorido(triphenylphosphane-κP)palladium(II)] chloroform disolvate
The title compound, [Pd(2)Cl(2)(C(6)H(5)S)(2)(C(18)H(15)P)(2)]·2CHCl(3), contains a centrosymmetric dinuclear palladium complex with the Pd(II) cation in a slightly distorted square-planar coordination environment. The Pd(II) cations are bridged by the S atoms of two benzenethiolate ligands with d...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793701/ https://www.ncbi.nlm.nih.gov/pubmed/24109288 http://dx.doi.org/10.1107/S1600536813019806 |
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author | Avila-Sorrosa, Alcives Reyes-Arellano, Alicia Germán-Acacio, Juan Manuel Reyes-Martínez, Reyna Morales-Morales, David |
author_facet | Avila-Sorrosa, Alcives Reyes-Arellano, Alicia Germán-Acacio, Juan Manuel Reyes-Martínez, Reyna Morales-Morales, David |
author_sort | Avila-Sorrosa, Alcives |
collection | PubMed |
description | The title compound, [Pd(2)Cl(2)(C(6)H(5)S)(2)(C(18)H(15)P)(2)]·2CHCl(3), contains a centrosymmetric dinuclear palladium complex with the Pd(II) cation in a slightly distorted square-planar coordination environment. The Pd(II) cations are bridged by the S atoms of two benzenethiolate ligands with different Pd—S distances [2.2970 (11) and 2.3676 (11) Å]. The coordination of the metal atom is completed by a chloride anion [2.3383 (11) Å] and a triphenylphosphane ligand [2.2787 (11) Å]. Weak C—H⋯Cl interactions are present between complex molecules and the CHCl(3) solvent molecule. The latter is disordered over two positions in a 0.792 (8):0.208 (8) ratio. The crystal under investigation was found to be twinned by nonmerohedry, with a fraction of 73.4 (1)% for the major twin component. |
format | Online Article Text |
id | pubmed-3793701 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37937012013-10-09 trans-Bis(μ-benzenethiolato-κ(2) S:S)bis[chlorido(triphenylphosphane-κP)palladium(II)] chloroform disolvate Avila-Sorrosa, Alcives Reyes-Arellano, Alicia Germán-Acacio, Juan Manuel Reyes-Martínez, Reyna Morales-Morales, David Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pd(2)Cl(2)(C(6)H(5)S)(2)(C(18)H(15)P)(2)]·2CHCl(3), contains a centrosymmetric dinuclear palladium complex with the Pd(II) cation in a slightly distorted square-planar coordination environment. The Pd(II) cations are bridged by the S atoms of two benzenethiolate ligands with different Pd—S distances [2.2970 (11) and 2.3676 (11) Å]. The coordination of the metal atom is completed by a chloride anion [2.3383 (11) Å] and a triphenylphosphane ligand [2.2787 (11) Å]. Weak C—H⋯Cl interactions are present between complex molecules and the CHCl(3) solvent molecule. The latter is disordered over two positions in a 0.792 (8):0.208 (8) ratio. The crystal under investigation was found to be twinned by nonmerohedry, with a fraction of 73.4 (1)% for the major twin component. International Union of Crystallography 2013-07-24 /pmc/articles/PMC3793701/ /pubmed/24109288 http://dx.doi.org/10.1107/S1600536813019806 Text en © Avila-Sorrosa et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Avila-Sorrosa, Alcives Reyes-Arellano, Alicia Germán-Acacio, Juan Manuel Reyes-Martínez, Reyna Morales-Morales, David trans-Bis(μ-benzenethiolato-κ(2) S:S)bis[chlorido(triphenylphosphane-κP)palladium(II)] chloroform disolvate |
title |
trans-Bis(μ-benzenethiolato-κ(2)
S:S)bis[chlorido(triphenylphosphane-κP)palladium(II)] chloroform disolvate |
title_full |
trans-Bis(μ-benzenethiolato-κ(2)
S:S)bis[chlorido(triphenylphosphane-κP)palladium(II)] chloroform disolvate |
title_fullStr |
trans-Bis(μ-benzenethiolato-κ(2)
S:S)bis[chlorido(triphenylphosphane-κP)palladium(II)] chloroform disolvate |
title_full_unstemmed |
trans-Bis(μ-benzenethiolato-κ(2)
S:S)bis[chlorido(triphenylphosphane-κP)palladium(II)] chloroform disolvate |
title_short |
trans-Bis(μ-benzenethiolato-κ(2)
S:S)bis[chlorido(triphenylphosphane-κP)palladium(II)] chloroform disolvate |
title_sort | trans-bis(μ-benzenethiolato-κ(2)
s:s)bis[chlorido(triphenylphosphane-κp)palladium(ii)] chloroform disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793701/ https://www.ncbi.nlm.nih.gov/pubmed/24109288 http://dx.doi.org/10.1107/S1600536813019806 |
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