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trans-Bis(μ-benzene­thiol­ato-κ(2) S:S)bis[chlorido­(tri­phenyl­phosphane-κP)palladium(II)] chloro­form disolvate

The title compound, [Pd(2)Cl(2)(C(6)H(5)S)(2)(C(18)H(15)P)(2)]·2CHCl(3), contains a centrosymmetric dinuclear palladium complex with the Pd(II) cation in a slightly distorted square-planar coordination environment. The Pd(II) cations are bridged by the S atoms of two benzene­thiol­ate ligands with d...

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Autores principales: Avila-Sorrosa, Alcives, Reyes-Arellano, Alicia, Germán-Acacio, Juan Manuel, Reyes-Martínez, Reyna, Morales-Morales, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793701/
https://www.ncbi.nlm.nih.gov/pubmed/24109288
http://dx.doi.org/10.1107/S1600536813019806
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author Avila-Sorrosa, Alcives
Reyes-Arellano, Alicia
Germán-Acacio, Juan Manuel
Reyes-Martínez, Reyna
Morales-Morales, David
author_facet Avila-Sorrosa, Alcives
Reyes-Arellano, Alicia
Germán-Acacio, Juan Manuel
Reyes-Martínez, Reyna
Morales-Morales, David
author_sort Avila-Sorrosa, Alcives
collection PubMed
description The title compound, [Pd(2)Cl(2)(C(6)H(5)S)(2)(C(18)H(15)P)(2)]·2CHCl(3), contains a centrosymmetric dinuclear palladium complex with the Pd(II) cation in a slightly distorted square-planar coordination environment. The Pd(II) cations are bridged by the S atoms of two benzene­thiol­ate ligands with different Pd—S distances [2.2970 (11) and 2.3676 (11) Å]. The coordination of the metal atom is completed by a chloride anion [2.3383 (11) Å] and a tri­phenyl­phosphane ligand [2.2787 (11) Å]. Weak C—H⋯Cl inter­actions are present between complex mol­ecules and the CHCl(3) solvent mol­ecule. The latter is disordered over two positions in a 0.792 (8):0.208 (8) ratio. The crystal under investigation was found to be twinned by nonmerohedry, with a fraction of 73.4 (1)% for the major twin component.
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spelling pubmed-37937012013-10-09 trans-Bis(μ-benzene­thiol­ato-κ(2) S:S)bis[chlorido­(tri­phenyl­phosphane-κP)palladium(II)] chloro­form disolvate Avila-Sorrosa, Alcives Reyes-Arellano, Alicia Germán-Acacio, Juan Manuel Reyes-Martínez, Reyna Morales-Morales, David Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pd(2)Cl(2)(C(6)H(5)S)(2)(C(18)H(15)P)(2)]·2CHCl(3), contains a centrosymmetric dinuclear palladium complex with the Pd(II) cation in a slightly distorted square-planar coordination environment. The Pd(II) cations are bridged by the S atoms of two benzene­thiol­ate ligands with different Pd—S distances [2.2970 (11) and 2.3676 (11) Å]. The coordination of the metal atom is completed by a chloride anion [2.3383 (11) Å] and a tri­phenyl­phosphane ligand [2.2787 (11) Å]. Weak C—H⋯Cl inter­actions are present between complex mol­ecules and the CHCl(3) solvent mol­ecule. The latter is disordered over two positions in a 0.792 (8):0.208 (8) ratio. The crystal under investigation was found to be twinned by nonmerohedry, with a fraction of 73.4 (1)% for the major twin component. International Union of Crystallography 2013-07-24 /pmc/articles/PMC3793701/ /pubmed/24109288 http://dx.doi.org/10.1107/S1600536813019806 Text en © Avila-Sorrosa et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Avila-Sorrosa, Alcives
Reyes-Arellano, Alicia
Germán-Acacio, Juan Manuel
Reyes-Martínez, Reyna
Morales-Morales, David
trans-Bis(μ-benzene­thiol­ato-κ(2) S:S)bis[chlorido­(tri­phenyl­phosphane-κP)palladium(II)] chloro­form disolvate
title trans-Bis(μ-benzene­thiol­ato-κ(2) S:S)bis[chlorido­(tri­phenyl­phosphane-κP)palladium(II)] chloro­form disolvate
title_full trans-Bis(μ-benzene­thiol­ato-κ(2) S:S)bis[chlorido­(tri­phenyl­phosphane-κP)palladium(II)] chloro­form disolvate
title_fullStr trans-Bis(μ-benzene­thiol­ato-κ(2) S:S)bis[chlorido­(tri­phenyl­phosphane-κP)palladium(II)] chloro­form disolvate
title_full_unstemmed trans-Bis(μ-benzene­thiol­ato-κ(2) S:S)bis[chlorido­(tri­phenyl­phosphane-κP)palladium(II)] chloro­form disolvate
title_short trans-Bis(μ-benzene­thiol­ato-κ(2) S:S)bis[chlorido­(tri­phenyl­phosphane-κP)palladium(II)] chloro­form disolvate
title_sort trans-bis(μ-benzene­thiol­ato-κ(2) s:s)bis[chlorido­(tri­phenyl­phosphane-κp)palladium(ii)] chloro­form disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793701/
https://www.ncbi.nlm.nih.gov/pubmed/24109288
http://dx.doi.org/10.1107/S1600536813019806
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