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Bis(cyclohexylammonium) tetrachlorido(oxalato)stannate(IV)
The title salt, (C(6)H(14)N)(2)[Sn(C(2)O(4))Cl(4)], was obtained as a by-product from the reaction between 2C(6)H(14)N(+)·C(2)O(4) (2−)·1.5H(2)O and SnCl(2)·2H(2)O. The cyclohexylammonium cation has a chair conformation. The complex anion consists of an oxalate anion chelating the SnCl(4) moiety,...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793702/ https://www.ncbi.nlm.nih.gov/pubmed/24109289 http://dx.doi.org/10.1107/S1600536813019284 |
| Sumario: | The title salt, (C(6)H(14)N)(2)[Sn(C(2)O(4))Cl(4)], was obtained as a by-product from the reaction between 2C(6)H(14)N(+)·C(2)O(4) (2−)·1.5H(2)O and SnCl(2)·2H(2)O. The cyclohexylammonium cation has a chair conformation. The complex anion consists of an oxalate anion chelating the SnCl(4) moiety, resulting in a distorted octahedral coordination sphere of the Sn(IV) atom with the O atoms in equatorial cis positions. In the crystal, cations and anions are linked through N—H⋯O and N—H⋯Cl interactions into a layered arrangement parallel to (100). |
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