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Bis(cyclohexylammonium) tetrachlorido(oxalato)stannate(IV)
The title salt, (C(6)H(14)N)(2)[Sn(C(2)O(4))Cl(4)], was obtained as a by-product from the reaction between 2C(6)H(14)N(+)·C(2)O(4) (2−)·1.5H(2)O and SnCl(2)·2H(2)O. The cyclohexylammonium cation has a chair conformation. The complex anion consists of an oxalate anion chelating the SnCl(4) moiety,...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793702/ https://www.ncbi.nlm.nih.gov/pubmed/24109289 http://dx.doi.org/10.1107/S1600536813019284 |
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author | Sarr, Modou Diasse-Sarr, Aminata Diallo, Waly Plasseraud, Laurent Cattey, Hélène |
author_facet | Sarr, Modou Diasse-Sarr, Aminata Diallo, Waly Plasseraud, Laurent Cattey, Hélène |
author_sort | Sarr, Modou |
collection | PubMed |
description | The title salt, (C(6)H(14)N)(2)[Sn(C(2)O(4))Cl(4)], was obtained as a by-product from the reaction between 2C(6)H(14)N(+)·C(2)O(4) (2−)·1.5H(2)O and SnCl(2)·2H(2)O. The cyclohexylammonium cation has a chair conformation. The complex anion consists of an oxalate anion chelating the SnCl(4) moiety, resulting in a distorted octahedral coordination sphere of the Sn(IV) atom with the O atoms in equatorial cis positions. In the crystal, cations and anions are linked through N—H⋯O and N—H⋯Cl interactions into a layered arrangement parallel to (100). |
format | Online Article Text |
id | pubmed-3793702 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37937022013-10-09 Bis(cyclohexylammonium) tetrachlorido(oxalato)stannate(IV) Sarr, Modou Diasse-Sarr, Aminata Diallo, Waly Plasseraud, Laurent Cattey, Hélène Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title salt, (C(6)H(14)N)(2)[Sn(C(2)O(4))Cl(4)], was obtained as a by-product from the reaction between 2C(6)H(14)N(+)·C(2)O(4) (2−)·1.5H(2)O and SnCl(2)·2H(2)O. The cyclohexylammonium cation has a chair conformation. The complex anion consists of an oxalate anion chelating the SnCl(4) moiety, resulting in a distorted octahedral coordination sphere of the Sn(IV) atom with the O atoms in equatorial cis positions. In the crystal, cations and anions are linked through N—H⋯O and N—H⋯Cl interactions into a layered arrangement parallel to (100). International Union of Crystallography 2013-07-27 /pmc/articles/PMC3793702/ /pubmed/24109289 http://dx.doi.org/10.1107/S1600536813019284 Text en © Sarr et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sarr, Modou Diasse-Sarr, Aminata Diallo, Waly Plasseraud, Laurent Cattey, Hélène Bis(cyclohexylammonium) tetrachlorido(oxalato)stannate(IV) |
title | Bis(cyclohexylammonium) tetrachlorido(oxalato)stannate(IV) |
title_full | Bis(cyclohexylammonium) tetrachlorido(oxalato)stannate(IV) |
title_fullStr | Bis(cyclohexylammonium) tetrachlorido(oxalato)stannate(IV) |
title_full_unstemmed | Bis(cyclohexylammonium) tetrachlorido(oxalato)stannate(IV) |
title_short | Bis(cyclohexylammonium) tetrachlorido(oxalato)stannate(IV) |
title_sort | bis(cyclohexylammonium) tetrachlorido(oxalato)stannate(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793702/ https://www.ncbi.nlm.nih.gov/pubmed/24109289 http://dx.doi.org/10.1107/S1600536813019284 |
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