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Bis(cyclo­hexyl­ammonium) tetra­chlorido­(oxalato)stannate(IV)

The title salt, (C(6)H(14)N)(2)[Sn(C(2)O(4))Cl(4)], was obtained as a by-product from the reaction between 2C(6)H(14)N(+)·C(2)O(4) (2−)·1.5H(2)O and SnCl(2)·2H(2)O. The cyclo­hexyl­ammonium cation has a chair conformation. The complex anion consists of an oxalate anion chelating the SnCl(4) moiety,...

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Autores principales: Sarr, Modou, Diasse-Sarr, Aminata, Diallo, Waly, Plasseraud, Laurent, Cattey, Hélène
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793702/
https://www.ncbi.nlm.nih.gov/pubmed/24109289
http://dx.doi.org/10.1107/S1600536813019284
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author Sarr, Modou
Diasse-Sarr, Aminata
Diallo, Waly
Plasseraud, Laurent
Cattey, Hélène
author_facet Sarr, Modou
Diasse-Sarr, Aminata
Diallo, Waly
Plasseraud, Laurent
Cattey, Hélène
author_sort Sarr, Modou
collection PubMed
description The title salt, (C(6)H(14)N)(2)[Sn(C(2)O(4))Cl(4)], was obtained as a by-product from the reaction between 2C(6)H(14)N(+)·C(2)O(4) (2−)·1.5H(2)O and SnCl(2)·2H(2)O. The cyclo­hexyl­ammonium cation has a chair conformation. The complex anion consists of an oxalate anion chelating the SnCl(4) moiety, resulting in a distorted octa­hedral coordination sphere of the Sn(IV) atom with the O atoms in equatorial cis positions. In the crystal, cations and anions are linked through N—H⋯O and N—H⋯Cl inter­actions into a layered arrangement parallel to (100).
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spelling pubmed-37937022013-10-09 Bis(cyclo­hexyl­ammonium) tetra­chlorido­(oxalato)stannate(IV) Sarr, Modou Diasse-Sarr, Aminata Diallo, Waly Plasseraud, Laurent Cattey, Hélène Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title salt, (C(6)H(14)N)(2)[Sn(C(2)O(4))Cl(4)], was obtained as a by-product from the reaction between 2C(6)H(14)N(+)·C(2)O(4) (2−)·1.5H(2)O and SnCl(2)·2H(2)O. The cyclo­hexyl­ammonium cation has a chair conformation. The complex anion consists of an oxalate anion chelating the SnCl(4) moiety, resulting in a distorted octa­hedral coordination sphere of the Sn(IV) atom with the O atoms in equatorial cis positions. In the crystal, cations and anions are linked through N—H⋯O and N—H⋯Cl inter­actions into a layered arrangement parallel to (100). International Union of Crystallography 2013-07-27 /pmc/articles/PMC3793702/ /pubmed/24109289 http://dx.doi.org/10.1107/S1600536813019284 Text en © Sarr et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sarr, Modou
Diasse-Sarr, Aminata
Diallo, Waly
Plasseraud, Laurent
Cattey, Hélène
Bis(cyclo­hexyl­ammonium) tetra­chlorido­(oxalato)stannate(IV)
title Bis(cyclo­hexyl­ammonium) tetra­chlorido­(oxalato)stannate(IV)
title_full Bis(cyclo­hexyl­ammonium) tetra­chlorido­(oxalato)stannate(IV)
title_fullStr Bis(cyclo­hexyl­ammonium) tetra­chlorido­(oxalato)stannate(IV)
title_full_unstemmed Bis(cyclo­hexyl­ammonium) tetra­chlorido­(oxalato)stannate(IV)
title_short Bis(cyclo­hexyl­ammonium) tetra­chlorido­(oxalato)stannate(IV)
title_sort bis(cyclo­hexyl­ammonium) tetra­chlorido­(oxalato)stannate(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793702/
https://www.ncbi.nlm.nih.gov/pubmed/24109289
http://dx.doi.org/10.1107/S1600536813019284
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AT plasseraudlaurent biscyclohexylammoniumtetrachloridooxalatostannateiv
AT catteyhelene biscyclohexylammoniumtetrachloridooxalatostannateiv