trans-Acetyl­dicarbon­yl(η(5)-cyclo­penta­dien­yl)[tris­(furan-2-yl)phosphane-κP]molybdenum(II)

The title compound, [Mo(C(5)H(5))(C(2)H(3)O)(C(12)H(9)O(3)P)(CO)(2)], was prepared by reaction of [Mo(C(5)H(5))(CO)(3)(CH(3))] with tris­(furan-2-yl)phosphane. The Mo(II) atom exhibits a four-legged piano-stool coordination geometry with the acetyl and phosphine ligands trans to each other. The O at...

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Detalles Bibliográficos
Autores principales: Whited, Matthew T., Bakker-Arkema, Julia G., Greenwald, Julia E., Morrill, Lucas A., Janzen, Daron E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793703/
https://www.ncbi.nlm.nih.gov/pubmed/24109290
http://dx.doi.org/10.1107/S160053681302059X
Descripción
Sumario:The title compound, [Mo(C(5)H(5))(C(2)H(3)O)(C(12)H(9)O(3)P)(CO)(2)], was prepared by reaction of [Mo(C(5)H(5))(CO)(3)(CH(3))] with tris­(furan-2-yl)phosphane. The Mo(II) atom exhibits a four-legged piano-stool coordination geometry with the acetyl and phosphine ligands trans to each other. The O atom of the acetyl ligand points down, away from the Cp ring. In the crystal, mol­ecules form centrosymmetrical dimers via π–π inter­actions between furyl rings [the centroid–centroid distance is 3.396 (4) Å]. The dimers are linked by C—H⋯O hydrogen bonds into layers parallel to (100).

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