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trans-Acetyldicarbonyl(η(5)-cyclopentadienyl)[tris(furan-2-yl)phosphane-κP]molybdenum(II)
The title compound, [Mo(C(5)H(5))(C(2)H(3)O)(C(12)H(9)O(3)P)(CO)(2)], was prepared by reaction of [Mo(C(5)H(5))(CO)(3)(CH(3))] with tris(furan-2-yl)phosphane. The Mo(II) atom exhibits a four-legged piano-stool coordination geometry with the acetyl and phosphine ligands trans to each other. The O at...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793703/ https://www.ncbi.nlm.nih.gov/pubmed/24109290 http://dx.doi.org/10.1107/S160053681302059X |
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author | Whited, Matthew T. Bakker-Arkema, Julia G. Greenwald, Julia E. Morrill, Lucas A. Janzen, Daron E. |
author_facet | Whited, Matthew T. Bakker-Arkema, Julia G. Greenwald, Julia E. Morrill, Lucas A. Janzen, Daron E. |
author_sort | Whited, Matthew T. |
collection | PubMed |
description | The title compound, [Mo(C(5)H(5))(C(2)H(3)O)(C(12)H(9)O(3)P)(CO)(2)], was prepared by reaction of [Mo(C(5)H(5))(CO)(3)(CH(3))] with tris(furan-2-yl)phosphane. The Mo(II) atom exhibits a four-legged piano-stool coordination geometry with the acetyl and phosphine ligands trans to each other. The O atom of the acetyl ligand points down, away from the Cp ring. In the crystal, molecules form centrosymmetrical dimers via π–π interactions between furyl rings [the centroid–centroid distance is 3.396 (4) Å]. The dimers are linked by C—H⋯O hydrogen bonds into layers parallel to (100). |
format | Online Article Text |
id | pubmed-3793703 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37937032013-10-09 trans-Acetyldicarbonyl(η(5)-cyclopentadienyl)[tris(furan-2-yl)phosphane-κP]molybdenum(II) Whited, Matthew T. Bakker-Arkema, Julia G. Greenwald, Julia E. Morrill, Lucas A. Janzen, Daron E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mo(C(5)H(5))(C(2)H(3)O)(C(12)H(9)O(3)P)(CO)(2)], was prepared by reaction of [Mo(C(5)H(5))(CO)(3)(CH(3))] with tris(furan-2-yl)phosphane. The Mo(II) atom exhibits a four-legged piano-stool coordination geometry with the acetyl and phosphine ligands trans to each other. The O atom of the acetyl ligand points down, away from the Cp ring. In the crystal, molecules form centrosymmetrical dimers via π–π interactions between furyl rings [the centroid–centroid distance is 3.396 (4) Å]. The dimers are linked by C—H⋯O hydrogen bonds into layers parallel to (100). International Union of Crystallography 2013-07-31 /pmc/articles/PMC3793703/ /pubmed/24109290 http://dx.doi.org/10.1107/S160053681302059X Text en © Whited et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Whited, Matthew T. Bakker-Arkema, Julia G. Greenwald, Julia E. Morrill, Lucas A. Janzen, Daron E. trans-Acetyldicarbonyl(η(5)-cyclopentadienyl)[tris(furan-2-yl)phosphane-κP]molybdenum(II) |
title |
trans-Acetyldicarbonyl(η(5)-cyclopentadienyl)[tris(furan-2-yl)phosphane-κP]molybdenum(II) |
title_full |
trans-Acetyldicarbonyl(η(5)-cyclopentadienyl)[tris(furan-2-yl)phosphane-κP]molybdenum(II) |
title_fullStr |
trans-Acetyldicarbonyl(η(5)-cyclopentadienyl)[tris(furan-2-yl)phosphane-κP]molybdenum(II) |
title_full_unstemmed |
trans-Acetyldicarbonyl(η(5)-cyclopentadienyl)[tris(furan-2-yl)phosphane-κP]molybdenum(II) |
title_short |
trans-Acetyldicarbonyl(η(5)-cyclopentadienyl)[tris(furan-2-yl)phosphane-κP]molybdenum(II) |
title_sort | trans-acetyldicarbonyl(η(5)-cyclopentadienyl)[tris(furan-2-yl)phosphane-κp]molybdenum(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793703/ https://www.ncbi.nlm.nih.gov/pubmed/24109290 http://dx.doi.org/10.1107/S160053681302059X |
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