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trans-Acetyl­dicarbon­yl(η(5)-cyclo­penta­dien­yl)[tris­(furan-2-yl)phosphane-κP]molybdenum(II)

The title compound, [Mo(C(5)H(5))(C(2)H(3)O)(C(12)H(9)O(3)P)(CO)(2)], was prepared by reaction of [Mo(C(5)H(5))(CO)(3)(CH(3))] with tris­(furan-2-yl)phosphane. The Mo(II) atom exhibits a four-legged piano-stool coordination geometry with the acetyl and phosphine ligands trans to each other. The O at...

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Autores principales: Whited, Matthew T., Bakker-Arkema, Julia G., Greenwald, Julia E., Morrill, Lucas A., Janzen, Daron E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793703/
https://www.ncbi.nlm.nih.gov/pubmed/24109290
http://dx.doi.org/10.1107/S160053681302059X
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author Whited, Matthew T.
Bakker-Arkema, Julia G.
Greenwald, Julia E.
Morrill, Lucas A.
Janzen, Daron E.
author_facet Whited, Matthew T.
Bakker-Arkema, Julia G.
Greenwald, Julia E.
Morrill, Lucas A.
Janzen, Daron E.
author_sort Whited, Matthew T.
collection PubMed
description The title compound, [Mo(C(5)H(5))(C(2)H(3)O)(C(12)H(9)O(3)P)(CO)(2)], was prepared by reaction of [Mo(C(5)H(5))(CO)(3)(CH(3))] with tris­(furan-2-yl)phosphane. The Mo(II) atom exhibits a four-legged piano-stool coordination geometry with the acetyl and phosphine ligands trans to each other. The O atom of the acetyl ligand points down, away from the Cp ring. In the crystal, mol­ecules form centrosymmetrical dimers via π–π inter­actions between furyl rings [the centroid–centroid distance is 3.396 (4) Å]. The dimers are linked by C—H⋯O hydrogen bonds into layers parallel to (100).
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spelling pubmed-37937032013-10-09 trans-Acetyl­dicarbon­yl(η(5)-cyclo­penta­dien­yl)[tris­(furan-2-yl)phosphane-κP]molybdenum(II) Whited, Matthew T. Bakker-Arkema, Julia G. Greenwald, Julia E. Morrill, Lucas A. Janzen, Daron E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mo(C(5)H(5))(C(2)H(3)O)(C(12)H(9)O(3)P)(CO)(2)], was prepared by reaction of [Mo(C(5)H(5))(CO)(3)(CH(3))] with tris­(furan-2-yl)phosphane. The Mo(II) atom exhibits a four-legged piano-stool coordination geometry with the acetyl and phosphine ligands trans to each other. The O atom of the acetyl ligand points down, away from the Cp ring. In the crystal, mol­ecules form centrosymmetrical dimers via π–π inter­actions between furyl rings [the centroid–centroid distance is 3.396 (4) Å]. The dimers are linked by C—H⋯O hydrogen bonds into layers parallel to (100). International Union of Crystallography 2013-07-31 /pmc/articles/PMC3793703/ /pubmed/24109290 http://dx.doi.org/10.1107/S160053681302059X Text en © Whited et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Whited, Matthew T.
Bakker-Arkema, Julia G.
Greenwald, Julia E.
Morrill, Lucas A.
Janzen, Daron E.
trans-Acetyl­dicarbon­yl(η(5)-cyclo­penta­dien­yl)[tris­(furan-2-yl)phosphane-κP]molybdenum(II)
title trans-Acetyl­dicarbon­yl(η(5)-cyclo­penta­dien­yl)[tris­(furan-2-yl)phosphane-κP]molybdenum(II)
title_full trans-Acetyl­dicarbon­yl(η(5)-cyclo­penta­dien­yl)[tris­(furan-2-yl)phosphane-κP]molybdenum(II)
title_fullStr trans-Acetyl­dicarbon­yl(η(5)-cyclo­penta­dien­yl)[tris­(furan-2-yl)phosphane-κP]molybdenum(II)
title_full_unstemmed trans-Acetyl­dicarbon­yl(η(5)-cyclo­penta­dien­yl)[tris­(furan-2-yl)phosphane-κP]molybdenum(II)
title_short trans-Acetyl­dicarbon­yl(η(5)-cyclo­penta­dien­yl)[tris­(furan-2-yl)phosphane-κP]molybdenum(II)
title_sort trans-acetyl­dicarbon­yl(η(5)-cyclo­penta­dien­yl)[tris­(furan-2-yl)phosphane-κp]molybdenum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793703/
https://www.ncbi.nlm.nih.gov/pubmed/24109290
http://dx.doi.org/10.1107/S160053681302059X
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