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3-{5-Bromo-2-[(tri­phenyl­phosphanyl­idene)amino]­phen­yl}-4,5-di­hydro-1,2,3-oxa­diazol-3-ylium-5-olate

In general, sydnone compounds are synthesized with an aromatic substituent at the N-3 position and this feature adds to the stability of the mesoionic five-membered heterocyclic ring. In the title compound, C(26)H(19)BrN(3)O(2)P, the aromatic substitutent is tri­phenyl­phosphine 4-bromo­phenyl­imide...

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Detalles Bibliográficos
Autores principales: Grossie, David, Harrison, Leanna, Turnbull, Kenneth
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793708/
https://www.ncbi.nlm.nih.gov/pubmed/24109295
http://dx.doi.org/10.1107/S1600536813017765
Descripción
Sumario:In general, sydnone compounds are synthesized with an aromatic substituent at the N-3 position and this feature adds to the stability of the mesoionic five-membered heterocyclic ring. In the title compound, C(26)H(19)BrN(3)O(2)P, the aromatic substitutent is tri­phenyl­phosphine 4-bromo­phenyl­imide. The dihedral angle between the planes of the sydnone and the attached phenyl ring is 45.98 (7)°. In the crystal, the mol­ecules packed as pairs in which the sydnone rings lie in parallel planes separated by 0.849 Å and sandwiched between two parallel phenyl rings. The mol­ecules inter­act through cyclic C—H⋯O=C hydrogen bonds.