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3-{5-Bromo-2-[(tri­phenyl­phosphanyl­idene)amino]­phen­yl}-4,5-di­hydro-1,2,3-oxa­diazol-3-ylium-5-olate

In general, sydnone compounds are synthesized with an aromatic substituent at the N-3 position and this feature adds to the stability of the mesoionic five-membered heterocyclic ring. In the title compound, C(26)H(19)BrN(3)O(2)P, the aromatic substitutent is tri­phenyl­phosphine 4-bromo­phenyl­imide...

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Detalles Bibliográficos
Autores principales: Grossie, David, Harrison, Leanna, Turnbull, Kenneth
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793708/
https://www.ncbi.nlm.nih.gov/pubmed/24109295
http://dx.doi.org/10.1107/S1600536813017765
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author Grossie, David
Harrison, Leanna
Turnbull, Kenneth
author_facet Grossie, David
Harrison, Leanna
Turnbull, Kenneth
author_sort Grossie, David
collection PubMed
description In general, sydnone compounds are synthesized with an aromatic substituent at the N-3 position and this feature adds to the stability of the mesoionic five-membered heterocyclic ring. In the title compound, C(26)H(19)BrN(3)O(2)P, the aromatic substitutent is tri­phenyl­phosphine 4-bromo­phenyl­imide. The dihedral angle between the planes of the sydnone and the attached phenyl ring is 45.98 (7)°. In the crystal, the mol­ecules packed as pairs in which the sydnone rings lie in parallel planes separated by 0.849 Å and sandwiched between two parallel phenyl rings. The mol­ecules inter­act through cyclic C—H⋯O=C hydrogen bonds.
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spelling pubmed-37937082013-10-09 3-{5-Bromo-2-[(tri­phenyl­phosphanyl­idene)amino]­phen­yl}-4,5-di­hydro-1,2,3-oxa­diazol-3-ylium-5-olate Grossie, David Harrison, Leanna Turnbull, Kenneth Acta Crystallogr Sect E Struct Rep Online Organic Papers In general, sydnone compounds are synthesized with an aromatic substituent at the N-3 position and this feature adds to the stability of the mesoionic five-membered heterocyclic ring. In the title compound, C(26)H(19)BrN(3)O(2)P, the aromatic substitutent is tri­phenyl­phosphine 4-bromo­phenyl­imide. The dihedral angle between the planes of the sydnone and the attached phenyl ring is 45.98 (7)°. In the crystal, the mol­ecules packed as pairs in which the sydnone rings lie in parallel planes separated by 0.849 Å and sandwiched between two parallel phenyl rings. The mol­ecules inter­act through cyclic C—H⋯O=C hydrogen bonds. International Union of Crystallography 2013-07-03 /pmc/articles/PMC3793708/ /pubmed/24109295 http://dx.doi.org/10.1107/S1600536813017765 Text en © Grossie et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Grossie, David
Harrison, Leanna
Turnbull, Kenneth
3-{5-Bromo-2-[(tri­phenyl­phosphanyl­idene)amino]­phen­yl}-4,5-di­hydro-1,2,3-oxa­diazol-3-ylium-5-olate
title 3-{5-Bromo-2-[(tri­phenyl­phosphanyl­idene)amino]­phen­yl}-4,5-di­hydro-1,2,3-oxa­diazol-3-ylium-5-olate
title_full 3-{5-Bromo-2-[(tri­phenyl­phosphanyl­idene)amino]­phen­yl}-4,5-di­hydro-1,2,3-oxa­diazol-3-ylium-5-olate
title_fullStr 3-{5-Bromo-2-[(tri­phenyl­phosphanyl­idene)amino]­phen­yl}-4,5-di­hydro-1,2,3-oxa­diazol-3-ylium-5-olate
title_full_unstemmed 3-{5-Bromo-2-[(tri­phenyl­phosphanyl­idene)amino]­phen­yl}-4,5-di­hydro-1,2,3-oxa­diazol-3-ylium-5-olate
title_short 3-{5-Bromo-2-[(tri­phenyl­phosphanyl­idene)amino]­phen­yl}-4,5-di­hydro-1,2,3-oxa­diazol-3-ylium-5-olate
title_sort 3-{5-bromo-2-[(tri­phenyl­phosphanyl­idene)amino]­phen­yl}-4,5-di­hydro-1,2,3-oxa­diazol-3-ylium-5-olate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793708/
https://www.ncbi.nlm.nih.gov/pubmed/24109295
http://dx.doi.org/10.1107/S1600536813017765
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