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(2S,3R)-3-(2-Bromo­phen­yl)-2-nitro-2,3,6,7-tetra­hydro-1-benzo­furan-4(5H)-one

The title compound, C(14)H(12)BrNO(4), has two chiral C atoms. The C atom next to the O atom in the di­hydro­furan ring has an S configuration, while the adjacent chiral C atom has an R configuration. The cyclo­hex-2-enone and di­hydro­furan rings both adopt envelope conformations, with the flap ato...

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Detalles Bibliográficos
Autores principales: Wang, Yifeng, Lou, Liuliu, Dong, Kun, Xu, Danqian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793709/
https://www.ncbi.nlm.nih.gov/pubmed/24109296
http://dx.doi.org/10.1107/S1600536813017698
Descripción
Sumario:The title compound, C(14)H(12)BrNO(4), has two chiral C atoms. The C atom next to the O atom in the di­hydro­furan ring has an S configuration, while the adjacent chiral C atom has an R configuration. The cyclo­hex-2-enone and di­hydro­furan rings both adopt envelope conformations, with the flap atoms (middle CH(2) in cyclo­hex-2-enone and NO(2)-substituted C in di­hydro­furan) lying 0.612 (3) and 0.295 (2) Å, respectively, from the mean plane of the remaining atoms. The dihedral angle between the mean planes of the furan and benzene rings is 80.0 (3)°. In the crystal, the mol­ecules are linked by C—H⋯O inter­actions, generating a three-dimensional network.