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2,2′-[(4-Methyl-2-phenyl­imidazolidine-1,3-di­yl)bis­(methyl­ene)]diphenol

The methyl-substituted imidazolidine ring of the title compound, C(24)H(26)N(2)O(2), adopts an envelope conformation with the N atom adjacent to the methyl­ene group as the flap. The meth­yl–ethyl­ene fragment in this ring is disordered over two positions with an occupancy ratio of 0.899 (4):0.101 (...

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Detalles Bibliográficos
Autores principales: Rivera, Augusto, Cárdenas, Lorena, Ríos-Motta, Jaime, Eigner, Václav, Dušek, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793710/
https://www.ncbi.nlm.nih.gov/pubmed/24109297
http://dx.doi.org/10.1107/S1600536813017893
Descripción
Sumario:The methyl-substituted imidazolidine ring of the title compound, C(24)H(26)N(2)O(2), adopts an envelope conformation with the N atom adjacent to the methyl­ene group as the flap. The meth­yl–ethyl­ene fragment in this ring is disordered over two positions with an occupancy ratio of 0.899 (4):0.101 (4). The hy­droxy­benzyl groups are inclined at 71.57 (15) and 69.97 (19)° to the mean plane of major disorder component of the heterocyclic ring with an inter­planar angle between the two hy­droxy­benzyl groups of 66.00 (5)°. The phenyl substit­uent approaches a nearly perpendicular orientation relative to the mean plane of the imidazolidine ring, making a dihedral angle of 75.60 (12)°. This conformation is stabilized by two intra­molecular O—H⋯N bonds, which generate S(6) ring motifs.