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2,2′-[(4-Methyl-2-phenylimidazolidine-1,3-diyl)bis(methylene)]diphenol
The methyl-substituted imidazolidine ring of the title compound, C(24)H(26)N(2)O(2), adopts an envelope conformation with the N atom adjacent to the methylene group as the flap. The methyl–ethylene fragment in this ring is disordered over two positions with an occupancy ratio of 0.899 (4):0.101 (...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793710/ https://www.ncbi.nlm.nih.gov/pubmed/24109297 http://dx.doi.org/10.1107/S1600536813017893 |
Sumario: | The methyl-substituted imidazolidine ring of the title compound, C(24)H(26)N(2)O(2), adopts an envelope conformation with the N atom adjacent to the methylene group as the flap. The methyl–ethylene fragment in this ring is disordered over two positions with an occupancy ratio of 0.899 (4):0.101 (4). The hydroxybenzyl groups are inclined at 71.57 (15) and 69.97 (19)° to the mean plane of major disorder component of the heterocyclic ring with an interplanar angle between the two hydroxybenzyl groups of 66.00 (5)°. The phenyl substituent approaches a nearly perpendicular orientation relative to the mean plane of the imidazolidine ring, making a dihedral angle of 75.60 (12)°. This conformation is stabilized by two intramolecular O—H⋯N bonds, which generate S(6) ring motifs. |
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