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5-Fluoro-3-phenyl-N′-(4-propylcyclohexylidene)-1H-indole-2-carbohydrazide
In the title compound, C(24)H(26)FN(3)O, the cyclohexane ring adopts a chair conformation; the propyl substituent is in an equatorial orientation and the bond-angle sum at the C atom bonded to the carbohydrazide N atom is 360.0°. The dihedral angle between the 1H-indole ring system and the phenyl r...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793713/ https://www.ncbi.nlm.nih.gov/pubmed/24109300 http://dx.doi.org/10.1107/S1600536813018333 |
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author | Çelikesir, Sevim Türktekin Akkurt, Mehmet Üstündağ, Gökçe Cihan Büyükgüngör, Orhan |
author_facet | Çelikesir, Sevim Türktekin Akkurt, Mehmet Üstündağ, Gökçe Cihan Büyükgüngör, Orhan |
author_sort | Çelikesir, Sevim Türktekin |
collection | PubMed |
description | In the title compound, C(24)H(26)FN(3)O, the cyclohexane ring adopts a chair conformation; the propyl substituent is in an equatorial orientation and the bond-angle sum at the C atom bonded to the carbohydrazide N atom is 360.0°. The dihedral angle between the 1H-indole ring system and the phenyl ring is 82.77 (13)°. A weak intramolecular C—H⋯π contact occurs. In the crystal, pairs of molecules related by a crystallographic twofold axis are linked by bifurcated N—H⋯(O,N) hydrogen bonds; a C—H⋯O interaction occurs between the same pair. The dimers are linked by C—H⋯F and C—H⋯π interactions, generating a three-dimensional network. |
format | Online Article Text |
id | pubmed-3793713 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37937132013-10-09 5-Fluoro-3-phenyl-N′-(4-propylcyclohexylidene)-1H-indole-2-carbohydrazide Çelikesir, Sevim Türktekin Akkurt, Mehmet Üstündağ, Gökçe Cihan Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(26)FN(3)O, the cyclohexane ring adopts a chair conformation; the propyl substituent is in an equatorial orientation and the bond-angle sum at the C atom bonded to the carbohydrazide N atom is 360.0°. The dihedral angle between the 1H-indole ring system and the phenyl ring is 82.77 (13)°. A weak intramolecular C—H⋯π contact occurs. In the crystal, pairs of molecules related by a crystallographic twofold axis are linked by bifurcated N—H⋯(O,N) hydrogen bonds; a C—H⋯O interaction occurs between the same pair. The dimers are linked by C—H⋯F and C—H⋯π interactions, generating a three-dimensional network. International Union of Crystallography 2013-07-06 /pmc/articles/PMC3793713/ /pubmed/24109300 http://dx.doi.org/10.1107/S1600536813018333 Text en © Çelikesir et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Çelikesir, Sevim Türktekin Akkurt, Mehmet Üstündağ, Gökçe Cihan Büyükgüngör, Orhan 5-Fluoro-3-phenyl-N′-(4-propylcyclohexylidene)-1H-indole-2-carbohydrazide |
title | 5-Fluoro-3-phenyl-N′-(4-propylcyclohexylidene)-1H-indole-2-carbohydrazide |
title_full | 5-Fluoro-3-phenyl-N′-(4-propylcyclohexylidene)-1H-indole-2-carbohydrazide |
title_fullStr | 5-Fluoro-3-phenyl-N′-(4-propylcyclohexylidene)-1H-indole-2-carbohydrazide |
title_full_unstemmed | 5-Fluoro-3-phenyl-N′-(4-propylcyclohexylidene)-1H-indole-2-carbohydrazide |
title_short | 5-Fluoro-3-phenyl-N′-(4-propylcyclohexylidene)-1H-indole-2-carbohydrazide |
title_sort | 5-fluoro-3-phenyl-n′-(4-propylcyclohexylidene)-1h-indole-2-carbohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793713/ https://www.ncbi.nlm.nih.gov/pubmed/24109300 http://dx.doi.org/10.1107/S1600536813018333 |
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