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5-Fluoro-3-phenyl-N′-(4-propyl­cyclo­hexyl­idene)-1H-indole-2-carbohydrazide

In the title compound, C(24)H(26)FN(3)O, the cyclo­hexane ring adopts a chair conformation; the propyl substituent is in an equatorial orientation and the bond-angle sum at the C atom bonded to the carbohydrazide N atom is 360.0°. The dihedral angle between the 1H-indole ring system and the phenyl r...

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Autores principales: Çelikesir, Sevim Türktekin, Akkurt, Mehmet, Üstündağ, Gökçe Cihan, Büyükgüngör, Orhan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793713/
https://www.ncbi.nlm.nih.gov/pubmed/24109300
http://dx.doi.org/10.1107/S1600536813018333
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author Çelikesir, Sevim Türktekin
Akkurt, Mehmet
Üstündağ, Gökçe Cihan
Büyükgüngör, Orhan
author_facet Çelikesir, Sevim Türktekin
Akkurt, Mehmet
Üstündağ, Gökçe Cihan
Büyükgüngör, Orhan
author_sort Çelikesir, Sevim Türktekin
collection PubMed
description In the title compound, C(24)H(26)FN(3)O, the cyclo­hexane ring adopts a chair conformation; the propyl substituent is in an equatorial orientation and the bond-angle sum at the C atom bonded to the carbohydrazide N atom is 360.0°. The dihedral angle between the 1H-indole ring system and the phenyl ring is 82.77 (13)°. A weak intra­molecular C—H⋯π contact occurs. In the crystal, pairs of mol­ecules related by a crystallographic twofold axis are linked by bifurcated N—H⋯(O,N) hydrogen bonds; a C—H⋯O inter­action occurs between the same pair. The dimers are linked by C—H⋯F and C—H⋯π inter­actions, generating a three-dimensional network.
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spelling pubmed-37937132013-10-09 5-Fluoro-3-phenyl-N′-(4-propyl­cyclo­hexyl­idene)-1H-indole-2-carbohydrazide Çelikesir, Sevim Türktekin Akkurt, Mehmet Üstündağ, Gökçe Cihan Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(26)FN(3)O, the cyclo­hexane ring adopts a chair conformation; the propyl substituent is in an equatorial orientation and the bond-angle sum at the C atom bonded to the carbohydrazide N atom is 360.0°. The dihedral angle between the 1H-indole ring system and the phenyl ring is 82.77 (13)°. A weak intra­molecular C—H⋯π contact occurs. In the crystal, pairs of mol­ecules related by a crystallographic twofold axis are linked by bifurcated N—H⋯(O,N) hydrogen bonds; a C—H⋯O inter­action occurs between the same pair. The dimers are linked by C—H⋯F and C—H⋯π inter­actions, generating a three-dimensional network. International Union of Crystallography 2013-07-06 /pmc/articles/PMC3793713/ /pubmed/24109300 http://dx.doi.org/10.1107/S1600536813018333 Text en © Çelikesir et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Çelikesir, Sevim Türktekin
Akkurt, Mehmet
Üstündağ, Gökçe Cihan
Büyükgüngör, Orhan
5-Fluoro-3-phenyl-N′-(4-propyl­cyclo­hexyl­idene)-1H-indole-2-carbohydrazide
title 5-Fluoro-3-phenyl-N′-(4-propyl­cyclo­hexyl­idene)-1H-indole-2-carbohydrazide
title_full 5-Fluoro-3-phenyl-N′-(4-propyl­cyclo­hexyl­idene)-1H-indole-2-carbohydrazide
title_fullStr 5-Fluoro-3-phenyl-N′-(4-propyl­cyclo­hexyl­idene)-1H-indole-2-carbohydrazide
title_full_unstemmed 5-Fluoro-3-phenyl-N′-(4-propyl­cyclo­hexyl­idene)-1H-indole-2-carbohydrazide
title_short 5-Fluoro-3-phenyl-N′-(4-propyl­cyclo­hexyl­idene)-1H-indole-2-carbohydrazide
title_sort 5-fluoro-3-phenyl-n′-(4-propyl­cyclo­hexyl­idene)-1h-indole-2-carbohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793713/
https://www.ncbi.nlm.nih.gov/pubmed/24109300
http://dx.doi.org/10.1107/S1600536813018333
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