Bifenox: methyl 5-(2,4-di­chloro­phen­oxy)-2-nitro­benzoate

In the title compound, the herbicide bifenox, C(14)H(9)Cl(2)NO(5), the dihedral angle between the dichlorobenzene and nitro­benzene rings is 78.79 (14)°. In the crystal, C—H⋯O hydrogen bonds give rise to a three-dimensional network structure in which there are both a π–π inter­action [ring centroid...

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Autores principales: Jeon, Youngeun, Kim, Jineun, Cho, Seonghwa, Kim, Tae Ho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793716/
https://www.ncbi.nlm.nih.gov/pubmed/24109303
http://dx.doi.org/10.1107/S1600536813018266
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author Jeon, Youngeun
Kim, Jineun
Cho, Seonghwa
Kim, Tae Ho
author_facet Jeon, Youngeun
Kim, Jineun
Cho, Seonghwa
Kim, Tae Ho
author_sort Jeon, Youngeun
collection PubMed
description In the title compound, the herbicide bifenox, C(14)H(9)Cl(2)NO(5), the dihedral angle between the dichlorobenzene and nitro­benzene rings is 78.79 (14)°. In the crystal, C—H⋯O hydrogen bonds give rise to a three-dimensional network structure in which there are both a π–π inter­action [ring centroid separation = 3.6212 (16) Å] and a C—Cl⋯π inter­action [Cl⋯ring centroid = 3.4754 (8) Å]. In addition, short Cl⋯Cl contacts [3.3767 (11) and 3.3946 (11) Å] are present.
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spelling pubmed-37937162013-10-09 Bifenox: methyl 5-(2,4-di­chloro­phen­oxy)-2-nitro­benzoate Jeon, Youngeun Kim, Jineun Cho, Seonghwa Kim, Tae Ho Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, the herbicide bifenox, C(14)H(9)Cl(2)NO(5), the dihedral angle between the dichlorobenzene and nitro­benzene rings is 78.79 (14)°. In the crystal, C—H⋯O hydrogen bonds give rise to a three-dimensional network structure in which there are both a π–π inter­action [ring centroid separation = 3.6212 (16) Å] and a C—Cl⋯π inter­action [Cl⋯ring centroid = 3.4754 (8) Å]. In addition, short Cl⋯Cl contacts [3.3767 (11) and 3.3946 (11) Å] are present. International Union of Crystallography 2013-07-06 /pmc/articles/PMC3793716/ /pubmed/24109303 http://dx.doi.org/10.1107/S1600536813018266 Text en © Jeon et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jeon, Youngeun
Kim, Jineun
Cho, Seonghwa
Kim, Tae Ho
Bifenox: methyl 5-(2,4-di­chloro­phen­oxy)-2-nitro­benzoate
title Bifenox: methyl 5-(2,4-di­chloro­phen­oxy)-2-nitro­benzoate
title_full Bifenox: methyl 5-(2,4-di­chloro­phen­oxy)-2-nitro­benzoate
title_fullStr Bifenox: methyl 5-(2,4-di­chloro­phen­oxy)-2-nitro­benzoate
title_full_unstemmed Bifenox: methyl 5-(2,4-di­chloro­phen­oxy)-2-nitro­benzoate
title_short Bifenox: methyl 5-(2,4-di­chloro­phen­oxy)-2-nitro­benzoate
title_sort bifenox: methyl 5-(2,4-di­chloro­phen­oxy)-2-nitro­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793716/
https://www.ncbi.nlm.nih.gov/pubmed/24109303
http://dx.doi.org/10.1107/S1600536813018266
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AT kimjineun bifenoxmethyl524dichlorophenoxy2nitrobenzoate
AT choseonghwa bifenoxmethyl524dichlorophenoxy2nitrobenzoate
AT kimtaeho bifenoxmethyl524dichlorophenoxy2nitrobenzoate

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