Methyl 3′-benzyl-4′-(2-chloro­phen­yl)-1′-methyl-2-oxo­spiro­[indoline-3,2′-pyrrolidine]-3′-carboxyl­ate

In the title compound, C(27)H(25)ClN(2)O(3), the methyl­pyrrolidine ring adopts an envelope conformation with the N atom at the flap. The mean plane of the pyrrolidine ring makes dihedral angles of 82.1 (1), 84.4 (1) and 79.8 (1)°, respectively, with the adjacent benzene ring, the mean plane of the...

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Autores principales: Anuradha, T., Devaraj, A., Seshadri, P. R., Bakthadoss, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793722/
https://www.ncbi.nlm.nih.gov/pubmed/24109309
http://dx.doi.org/10.1107/S1600536813018424
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author Anuradha, T.
Devaraj, A.
Seshadri, P. R.
Bakthadoss, M.
author_facet Anuradha, T.
Devaraj, A.
Seshadri, P. R.
Bakthadoss, M.
author_sort Anuradha, T.
collection PubMed
description In the title compound, C(27)H(25)ClN(2)O(3), the methyl­pyrrolidine ring adopts an envelope conformation with the N atom at the flap. The mean plane of the pyrrolidine ring makes dihedral angles of 82.1 (1), 84.4 (1) and 79.8 (1)°, respectively, with the adjacent benzene ring, the mean plane of the indoline ring system and the phenyl ring. The mol­ecular structure is stabilized by intra­molecular C—H⋯O hydrogen bonds. In the crystal, mol­ecules are linked into chains along [101] by N—H⋯O hydrogen bonds. C—H⋯π inter­actions are observed between the chains.
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spelling pubmed-37937222013-10-09 Methyl 3′-benzyl-4′-(2-chloro­phen­yl)-1′-methyl-2-oxo­spiro­[indoline-3,2′-pyrrolidine]-3′-carboxyl­ate Anuradha, T. Devaraj, A. Seshadri, P. R. Bakthadoss, M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(27)H(25)ClN(2)O(3), the methyl­pyrrolidine ring adopts an envelope conformation with the N atom at the flap. The mean plane of the pyrrolidine ring makes dihedral angles of 82.1 (1), 84.4 (1) and 79.8 (1)°, respectively, with the adjacent benzene ring, the mean plane of the indoline ring system and the phenyl ring. The mol­ecular structure is stabilized by intra­molecular C—H⋯O hydrogen bonds. In the crystal, mol­ecules are linked into chains along [101] by N—H⋯O hydrogen bonds. C—H⋯π inter­actions are observed between the chains. International Union of Crystallography 2013-07-06 /pmc/articles/PMC3793722/ /pubmed/24109309 http://dx.doi.org/10.1107/S1600536813018424 Text en © Anuradha et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Anuradha, T.
Devaraj, A.
Seshadri, P. R.
Bakthadoss, M.
Methyl 3′-benzyl-4′-(2-chloro­phen­yl)-1′-methyl-2-oxo­spiro­[indoline-3,2′-pyrrolidine]-3′-carboxyl­ate
title Methyl 3′-benzyl-4′-(2-chloro­phen­yl)-1′-methyl-2-oxo­spiro­[indoline-3,2′-pyrrolidine]-3′-carboxyl­ate
title_full Methyl 3′-benzyl-4′-(2-chloro­phen­yl)-1′-methyl-2-oxo­spiro­[indoline-3,2′-pyrrolidine]-3′-carboxyl­ate
title_fullStr Methyl 3′-benzyl-4′-(2-chloro­phen­yl)-1′-methyl-2-oxo­spiro­[indoline-3,2′-pyrrolidine]-3′-carboxyl­ate
title_full_unstemmed Methyl 3′-benzyl-4′-(2-chloro­phen­yl)-1′-methyl-2-oxo­spiro­[indoline-3,2′-pyrrolidine]-3′-carboxyl­ate
title_short Methyl 3′-benzyl-4′-(2-chloro­phen­yl)-1′-methyl-2-oxo­spiro­[indoline-3,2′-pyrrolidine]-3′-carboxyl­ate
title_sort methyl 3′-benzyl-4′-(2-chloro­phen­yl)-1′-methyl-2-oxo­spiro­[indoline-3,2′-pyrrolidine]-3′-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793722/
https://www.ncbi.nlm.nih.gov/pubmed/24109309
http://dx.doi.org/10.1107/S1600536813018424
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AT devaraja methyl3benzyl42chlorophenyl1methyl2oxospiroindoline32pyrrolidine3carboxylate
AT seshadripr methyl3benzyl42chlorophenyl1methyl2oxospiroindoline32pyrrolidine3carboxylate
AT bakthadossm methyl3benzyl42chlorophenyl1methyl2oxospiroindoline32pyrrolidine3carboxylate

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