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2,2′-{[2-(2-Chloro­phen­yl)-4-methyl­imidazolidine-1,3-di­yl]bis­(methyl­ene)}diphenol

In the title compound, C(24)H(25)ClN(2)O(2), the 2-hy­droxy­benzyl substituents and the 2-chloro­phenyl group occupy the sterically preferred equatorial positions, whereas the methyl group occupies the axial position. The imidazolidine ring adopts an envelope conformation with one of the N atoms adj...

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Detalles Bibliográficos
Autores principales: Rivera, Augusto, Cárdenas, Lorena, Ríos-Motta, Jaime, Kučeraková, Monika, Dušek, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793727/
https://www.ncbi.nlm.nih.gov/pubmed/24109314
http://dx.doi.org/10.1107/S1600536813017923
Descripción
Sumario:In the title compound, C(24)H(25)ClN(2)O(2), the 2-hy­droxy­benzyl substituents and the 2-chloro­phenyl group occupy the sterically preferred equatorial positions, whereas the methyl group occupies the axial position. The imidazolidine ring adopts an envelope conformation with one of the N atoms adjacent to the methylene group as the flap. The chloro­phenyl substit­uent approaches a nearly perpendicular orientation relative to the mean plane of the imidazolidine ring, making a dihedral angle of 73.44 (12)° and the Cl atom is almost coplanar with the C atom bearing the chloro­phenyl substituent [Cl—C—C—C torsion angle = 1.1 (3)°]. The hy­droxy­benzyl groups make dihedral angles of 71.23 (15) and 69.13 (19)° with the mean plane of the heterocyclic ring. The dihedral angle between the two hy­droxy­benzyl groups is 69.61 (12)°. The mol­ecular structure features two intra­molecular O—H⋯N hydrogen bonds with graph-set motif S(6) between the phenolic hydroxyl groups and N atoms.