2,3-Tri­methyl­ene-7,8-di­hydro­pyrrolo­[1,2-a]thieno[2,3-d]pyrimidin-4(6H)-one

The title mol­ecule, C(12)H(12)N(2)OS, is planar, with an r.m.s. deviation of 0.04 Å. In the crystal, the N atom adjacent to the carbonyl group is sp (2)-hybridized. The crystal structure is stabilized by π–π stacking inter­actions observed between thio­phene and pyrimidinone rings of c-glide-relate...

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Autores principales: Bozorov, Khurshed, Elmuradov, Burkhon, Shakhidoyatov, Khusnutdin, Aisa, Haji Akber, Tashkhodjaev, Bakhodir
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793729/
https://www.ncbi.nlm.nih.gov/pubmed/24109316
http://dx.doi.org/10.1107/S1600536813017935
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author Bozorov, Khurshed
Elmuradov, Burkhon
Shakhidoyatov, Khusnutdin
Aisa, Haji Akber
Tashkhodjaev, Bakhodir
author_facet Bozorov, Khurshed
Elmuradov, Burkhon
Shakhidoyatov, Khusnutdin
Aisa, Haji Akber
Tashkhodjaev, Bakhodir
author_sort Bozorov, Khurshed
collection PubMed
description The title mol­ecule, C(12)H(12)N(2)OS, is planar, with an r.m.s. deviation of 0.04 Å. In the crystal, the N atom adjacent to the carbonyl group is sp (2)-hybridized. The crystal structure is stabilized by π–π stacking inter­actions observed between thio­phene and pyrimidinone rings of c-glide-related mol­ecules [centroid–centroid distance = 3.9554 (13) Å] and by C—H⋯π inter­actions, forming an infinite chain along the c-axis direction.
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spelling pubmed-37937292013-10-09 2,3-Tri­methyl­ene-7,8-di­hydro­pyrrolo­[1,2-a]thieno[2,3-d]pyrimidin-4(6H)-one Bozorov, Khurshed Elmuradov, Burkhon Shakhidoyatov, Khusnutdin Aisa, Haji Akber Tashkhodjaev, Bakhodir Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(12)H(12)N(2)OS, is planar, with an r.m.s. deviation of 0.04 Å. In the crystal, the N atom adjacent to the carbonyl group is sp (2)-hybridized. The crystal structure is stabilized by π–π stacking inter­actions observed between thio­phene and pyrimidinone rings of c-glide-related mol­ecules [centroid–centroid distance = 3.9554 (13) Å] and by C—H⋯π inter­actions, forming an infinite chain along the c-axis direction. International Union of Crystallography 2013-07-10 /pmc/articles/PMC3793729/ /pubmed/24109316 http://dx.doi.org/10.1107/S1600536813017935 Text en © Bozorov et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bozorov, Khurshed
Elmuradov, Burkhon
Shakhidoyatov, Khusnutdin
Aisa, Haji Akber
Tashkhodjaev, Bakhodir
2,3-Tri­methyl­ene-7,8-di­hydro­pyrrolo­[1,2-a]thieno[2,3-d]pyrimidin-4(6H)-one
title 2,3-Tri­methyl­ene-7,8-di­hydro­pyrrolo­[1,2-a]thieno[2,3-d]pyrimidin-4(6H)-one
title_full 2,3-Tri­methyl­ene-7,8-di­hydro­pyrrolo­[1,2-a]thieno[2,3-d]pyrimidin-4(6H)-one
title_fullStr 2,3-Tri­methyl­ene-7,8-di­hydro­pyrrolo­[1,2-a]thieno[2,3-d]pyrimidin-4(6H)-one
title_full_unstemmed 2,3-Tri­methyl­ene-7,8-di­hydro­pyrrolo­[1,2-a]thieno[2,3-d]pyrimidin-4(6H)-one
title_short 2,3-Tri­methyl­ene-7,8-di­hydro­pyrrolo­[1,2-a]thieno[2,3-d]pyrimidin-4(6H)-one
title_sort 2,3-tri­methyl­ene-7,8-di­hydro­pyrrolo­[1,2-a]thieno[2,3-d]pyrimidin-4(6h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793729/
https://www.ncbi.nlm.nih.gov/pubmed/24109316
http://dx.doi.org/10.1107/S1600536813017935
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