5-[(4-Benzyl-1H-1,2,3-triazol-1-yl)meth­yl]-5H-dibenzo[b,f]azepine

In the title compound, C(24)H(20)N(4), the azepine ring adopts a boat conformation and the dihedral angle between the benzene rings fused to it is 57.95 (8)°. The bond-angle sum at the azepine N atom is 346.6°, indicating a significant deviation from planarity. The triazole ring subtends a dihedral...

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Detalles Bibliográficos
Autores principales: Manjunath, B. C., Vinay Kumar, K. S., Madan Kumar, S., Sadashiva, M. P., Lokanath, N. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793737/
https://www.ncbi.nlm.nih.gov/pubmed/24109324
http://dx.doi.org/10.1107/S1600536813018412
Descripción
Sumario:In the title compound, C(24)H(20)N(4), the azepine ring adopts a boat conformation and the dihedral angle between the benzene rings fused to it is 57.95 (8)°. The bond-angle sum at the azepine N atom is 346.6°, indicating a significant deviation from planarity. The triazole ring subtends a dihedral angle of 71.45 (10)° with the terminal phenyl group. A weak intra­molecular C—H⋯N(a) (a = azepine) inter­action occurs, which closes an S(6) ring.

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