5-[(4-Benzyl-1H-1,2,3-triazol-1-yl)meth­yl]-5H-dibenzo[b,f]azepine

In the title compound, C(24)H(20)N(4), the azepine ring adopts a boat conformation and the dihedral angle between the benzene rings fused to it is 57.95 (8)°. The bond-angle sum at the azepine N atom is 346.6°, indicating a significant deviation from planarity. The triazole ring subtends a dihedral...

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Detalles Bibliográficos
Autores principales: Manjunath, B. C., Vinay Kumar, K. S., Madan Kumar, S., Sadashiva, M. P., Lokanath, N. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793737/
https://www.ncbi.nlm.nih.gov/pubmed/24109324
http://dx.doi.org/10.1107/S1600536813018412
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author Manjunath, B. C.
Vinay Kumar, K. S.
Madan Kumar, S.
Sadashiva, M. P.
Lokanath, N. K.
author_facet Manjunath, B. C.
Vinay Kumar, K. S.
Madan Kumar, S.
Sadashiva, M. P.
Lokanath, N. K.
author_sort Manjunath, B. C.
collection PubMed
description In the title compound, C(24)H(20)N(4), the azepine ring adopts a boat conformation and the dihedral angle between the benzene rings fused to it is 57.95 (8)°. The bond-angle sum at the azepine N atom is 346.6°, indicating a significant deviation from planarity. The triazole ring subtends a dihedral angle of 71.45 (10)° with the terminal phenyl group. A weak intra­molecular C—H⋯N(a) (a = azepine) inter­action occurs, which closes an S(6) ring.
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spelling pubmed-37937372013-10-09 5-[(4-Benzyl-1H-1,2,3-triazol-1-yl)meth­yl]-5H-dibenzo[b,f]azepine Manjunath, B. C. Vinay Kumar, K. S. Madan Kumar, S. Sadashiva, M. P. Lokanath, N. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(20)N(4), the azepine ring adopts a boat conformation and the dihedral angle between the benzene rings fused to it is 57.95 (8)°. The bond-angle sum at the azepine N atom is 346.6°, indicating a significant deviation from planarity. The triazole ring subtends a dihedral angle of 71.45 (10)° with the terminal phenyl group. A weak intra­molecular C—H⋯N(a) (a = azepine) inter­action occurs, which closes an S(6) ring. International Union of Crystallography 2013-07-10 /pmc/articles/PMC3793737/ /pubmed/24109324 http://dx.doi.org/10.1107/S1600536813018412 Text en © Manjunath et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Manjunath, B. C.
Vinay Kumar, K. S.
Madan Kumar, S.
Sadashiva, M. P.
Lokanath, N. K.
5-[(4-Benzyl-1H-1,2,3-triazol-1-yl)meth­yl]-5H-dibenzo[b,f]azepine
title 5-[(4-Benzyl-1H-1,2,3-triazol-1-yl)meth­yl]-5H-dibenzo[b,f]azepine
title_full 5-[(4-Benzyl-1H-1,2,3-triazol-1-yl)meth­yl]-5H-dibenzo[b,f]azepine
title_fullStr 5-[(4-Benzyl-1H-1,2,3-triazol-1-yl)meth­yl]-5H-dibenzo[b,f]azepine
title_full_unstemmed 5-[(4-Benzyl-1H-1,2,3-triazol-1-yl)meth­yl]-5H-dibenzo[b,f]azepine
title_short 5-[(4-Benzyl-1H-1,2,3-triazol-1-yl)meth­yl]-5H-dibenzo[b,f]azepine
title_sort 5-[(4-benzyl-1h-1,2,3-triazol-1-yl)meth­yl]-5h-dibenzo[b,f]azepine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793737/
https://www.ncbi.nlm.nih.gov/pubmed/24109324
http://dx.doi.org/10.1107/S1600536813018412
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