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2-Amino-4,6-di­methyl­pyrimidine–sorbic acid (1/1)

In the crystal of the title compound, C(6)H(9)N(3)·C(6)H(8)O(2), the 2-amino-4,6-di­methyl­pyrimidine and sorbic acid mol­ecules are linked through N—H⋯O and O—H⋯N hydrogen bonds, which generate a cyclic bimolecular heterosynthon with an R (2) (2)(8) graph-set motif. Further, two inversion-related p...

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Detalles Bibliográficos
Autores principales: Gomathi, Sundaramoorthy, Muthiah, Packianathan Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793739/
https://www.ncbi.nlm.nih.gov/pubmed/24109326
http://dx.doi.org/10.1107/S1600536813018175
Descripción
Sumario:In the crystal of the title compound, C(6)H(9)N(3)·C(6)H(8)O(2), the 2-amino-4,6-di­methyl­pyrimidine and sorbic acid mol­ecules are linked through N—H⋯O and O—H⋯N hydrogen bonds, which generate a cyclic bimolecular heterosynthon with an R (2) (2)(8) graph-set motif. Further, two inversion-related pyrimidine mol­ecules are base-paired via a pair of N—H⋯N hydrogen bonds, forming a cyclic bimolecular homosynthon with a graph-set of R (2) (2)(8). A discrete hetero tetra­meric supra­molecular unit along the b axis is formed by the fusion of two heterosynthons and one homosynthon. An aromatic π–π inter­action [centroid–centroid distance = 3.7945 (16) Å] is observed between these tetra­meric units.