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2-Amino-4,6-di­methyl­pyrimidine–sorbic acid (1/1)

In the crystal of the title compound, C(6)H(9)N(3)·C(6)H(8)O(2), the 2-amino-4,6-di­methyl­pyrimidine and sorbic acid mol­ecules are linked through N—H⋯O and O—H⋯N hydrogen bonds, which generate a cyclic bimolecular heterosynthon with an R (2) (2)(8) graph-set motif. Further, two inversion-related p...

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Detalles Bibliográficos
Autores principales: Gomathi, Sundaramoorthy, Muthiah, Packianathan Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793739/
https://www.ncbi.nlm.nih.gov/pubmed/24109326
http://dx.doi.org/10.1107/S1600536813018175
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author Gomathi, Sundaramoorthy
Muthiah, Packianathan Thomas
author_facet Gomathi, Sundaramoorthy
Muthiah, Packianathan Thomas
author_sort Gomathi, Sundaramoorthy
collection PubMed
description In the crystal of the title compound, C(6)H(9)N(3)·C(6)H(8)O(2), the 2-amino-4,6-di­methyl­pyrimidine and sorbic acid mol­ecules are linked through N—H⋯O and O—H⋯N hydrogen bonds, which generate a cyclic bimolecular heterosynthon with an R (2) (2)(8) graph-set motif. Further, two inversion-related pyrimidine mol­ecules are base-paired via a pair of N—H⋯N hydrogen bonds, forming a cyclic bimolecular homosynthon with a graph-set of R (2) (2)(8). A discrete hetero tetra­meric supra­molecular unit along the b axis is formed by the fusion of two heterosynthons and one homosynthon. An aromatic π–π inter­action [centroid–centroid distance = 3.7945 (16) Å] is observed between these tetra­meric units.
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spelling pubmed-37937392013-10-09 2-Amino-4,6-di­methyl­pyrimidine–sorbic acid (1/1) Gomathi, Sundaramoorthy Muthiah, Packianathan Thomas Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal of the title compound, C(6)H(9)N(3)·C(6)H(8)O(2), the 2-amino-4,6-di­methyl­pyrimidine and sorbic acid mol­ecules are linked through N—H⋯O and O—H⋯N hydrogen bonds, which generate a cyclic bimolecular heterosynthon with an R (2) (2)(8) graph-set motif. Further, two inversion-related pyrimidine mol­ecules are base-paired via a pair of N—H⋯N hydrogen bonds, forming a cyclic bimolecular homosynthon with a graph-set of R (2) (2)(8). A discrete hetero tetra­meric supra­molecular unit along the b axis is formed by the fusion of two heterosynthons and one homosynthon. An aromatic π–π inter­action [centroid–centroid distance = 3.7945 (16) Å] is observed between these tetra­meric units. International Union of Crystallography 2013-07-10 /pmc/articles/PMC3793739/ /pubmed/24109326 http://dx.doi.org/10.1107/S1600536813018175 Text en © Gomathi and Muthiah 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gomathi, Sundaramoorthy
Muthiah, Packianathan Thomas
2-Amino-4,6-di­methyl­pyrimidine–sorbic acid (1/1)
title 2-Amino-4,6-di­methyl­pyrimidine–sorbic acid (1/1)
title_full 2-Amino-4,6-di­methyl­pyrimidine–sorbic acid (1/1)
title_fullStr 2-Amino-4,6-di­methyl­pyrimidine–sorbic acid (1/1)
title_full_unstemmed 2-Amino-4,6-di­methyl­pyrimidine–sorbic acid (1/1)
title_short 2-Amino-4,6-di­methyl­pyrimidine–sorbic acid (1/1)
title_sort 2-amino-4,6-di­methyl­pyrimidine–sorbic acid (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793739/
https://www.ncbi.nlm.nih.gov/pubmed/24109326
http://dx.doi.org/10.1107/S1600536813018175
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