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4-Sulfamoylanilinium perchlorate
In the crystal of the title salt, C(6)H(9)N(2)O(2)S(+)·ClO(4) (−), the components are linked by N—H⋯O hydrogen bonds, forming a three-dimensional network. The cations are connected along a and b axes, leading to linear and zigzag C(3) and C(8) chain motifs, respectively. A cation–anion interaction...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793740/ https://www.ncbi.nlm.nih.gov/pubmed/24109327 http://dx.doi.org/10.1107/S1600536813017972 |
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author | Anitha, R. Athimoolam, S. Gunasekaran, M. Sridhar, B. |
author_facet | Anitha, R. Athimoolam, S. Gunasekaran, M. Sridhar, B. |
author_sort | Anitha, R. |
collection | PubMed |
description | In the crystal of the title salt, C(6)H(9)N(2)O(2)S(+)·ClO(4) (−), the components are linked by N—H⋯O hydrogen bonds, forming a three-dimensional network. The cations are connected along a and b axes, leading to linear and zigzag C(3) and C(8) chain motifs, respectively. A cation–anion interaction along the c axis leads to a C (2) (2)(12) chain motif. R (3) (3)(18) and R (3) (3)(20) ring motifs are observed as cation–anion-type interactions. These hydrogen-bonding ring and chain motifs are localized at z = 0 or 1, leading to alternate hydrophilic and hydrophobic regions along the c axis as a result of the stacking of anions and the aromatic cationic parts. |
format | Online Article Text |
id | pubmed-3793740 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37937402013-10-09 4-Sulfamoylanilinium perchlorate Anitha, R. Athimoolam, S. Gunasekaran, M. Sridhar, B. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal of the title salt, C(6)H(9)N(2)O(2)S(+)·ClO(4) (−), the components are linked by N—H⋯O hydrogen bonds, forming a three-dimensional network. The cations are connected along a and b axes, leading to linear and zigzag C(3) and C(8) chain motifs, respectively. A cation–anion interaction along the c axis leads to a C (2) (2)(12) chain motif. R (3) (3)(18) and R (3) (3)(20) ring motifs are observed as cation–anion-type interactions. These hydrogen-bonding ring and chain motifs are localized at z = 0 or 1, leading to alternate hydrophilic and hydrophobic regions along the c axis as a result of the stacking of anions and the aromatic cationic parts. International Union of Crystallography 2013-07-10 /pmc/articles/PMC3793740/ /pubmed/24109327 http://dx.doi.org/10.1107/S1600536813017972 Text en © Anitha et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Anitha, R. Athimoolam, S. Gunasekaran, M. Sridhar, B. 4-Sulfamoylanilinium perchlorate |
title | 4-Sulfamoylanilinium perchlorate |
title_full | 4-Sulfamoylanilinium perchlorate |
title_fullStr | 4-Sulfamoylanilinium perchlorate |
title_full_unstemmed | 4-Sulfamoylanilinium perchlorate |
title_short | 4-Sulfamoylanilinium perchlorate |
title_sort | 4-sulfamoylanilinium perchlorate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793740/ https://www.ncbi.nlm.nih.gov/pubmed/24109327 http://dx.doi.org/10.1107/S1600536813017972 |
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