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4-Sulfamoylanilinium perchlorate

In the crystal of the title salt, C(6)H(9)N(2)O(2)S(+)·ClO(4) (−), the components are linked by N—H⋯O hydrogen bonds, forming a three-dimensional network. The cations are connected along a and b axes, leading to linear and zigzag C(3) and C(8) chain motifs, respectively. A cation–anion inter­action...

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Autores principales: Anitha, R., Athimoolam, S., Gunasekaran, M., Sridhar, B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793740/
https://www.ncbi.nlm.nih.gov/pubmed/24109327
http://dx.doi.org/10.1107/S1600536813017972
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author Anitha, R.
Athimoolam, S.
Gunasekaran, M.
Sridhar, B.
author_facet Anitha, R.
Athimoolam, S.
Gunasekaran, M.
Sridhar, B.
author_sort Anitha, R.
collection PubMed
description In the crystal of the title salt, C(6)H(9)N(2)O(2)S(+)·ClO(4) (−), the components are linked by N—H⋯O hydrogen bonds, forming a three-dimensional network. The cations are connected along a and b axes, leading to linear and zigzag C(3) and C(8) chain motifs, respectively. A cation–anion inter­action along the c axis leads to a C (2) (2)(12) chain motif. R (3) (3)(18) and R (3) (3)(20) ring motifs are observed as cation–anion-type inter­actions. These hydrogen-bonding ring and chain motifs are localized at z = 0 or 1, leading to alternate hydro­philic and hydro­phobic regions along the c axis as a result of the stacking of anions and the aromatic cationic parts.
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spelling pubmed-37937402013-10-09 4-Sulfamoylanilinium perchlorate Anitha, R. Athimoolam, S. Gunasekaran, M. Sridhar, B. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal of the title salt, C(6)H(9)N(2)O(2)S(+)·ClO(4) (−), the components are linked by N—H⋯O hydrogen bonds, forming a three-dimensional network. The cations are connected along a and b axes, leading to linear and zigzag C(3) and C(8) chain motifs, respectively. A cation–anion inter­action along the c axis leads to a C (2) (2)(12) chain motif. R (3) (3)(18) and R (3) (3)(20) ring motifs are observed as cation–anion-type inter­actions. These hydrogen-bonding ring and chain motifs are localized at z = 0 or 1, leading to alternate hydro­philic and hydro­phobic regions along the c axis as a result of the stacking of anions and the aromatic cationic parts. International Union of Crystallography 2013-07-10 /pmc/articles/PMC3793740/ /pubmed/24109327 http://dx.doi.org/10.1107/S1600536813017972 Text en © Anitha et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Anitha, R.
Athimoolam, S.
Gunasekaran, M.
Sridhar, B.
4-Sulfamoylanilinium perchlorate
title 4-Sulfamoylanilinium perchlorate
title_full 4-Sulfamoylanilinium perchlorate
title_fullStr 4-Sulfamoylanilinium perchlorate
title_full_unstemmed 4-Sulfamoylanilinium perchlorate
title_short 4-Sulfamoylanilinium perchlorate
title_sort 4-sulfamoylanilinium perchlorate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793740/
https://www.ncbi.nlm.nih.gov/pubmed/24109327
http://dx.doi.org/10.1107/S1600536813017972
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