1,4-Bis(2-diazo­acet­yl)piperazine

The asymmetric unit of the title compound, C(8)H(10)N(6)O(2), contains one-half mol­ecule, which is completed by a crystallographic center of symmetry. The piperazine ring adopts a chair conformation. In the crystal, weak C—H⋯O inter­actions link the mol­ecules into layers parallel to the bc plane....

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Detalles Bibliográficos
Autores principales: Kaupang, Åsmund, Görbitz, Carl Henrik, Bonge-Hansen, Tore
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793744/
https://www.ncbi.nlm.nih.gov/pubmed/24109331
http://dx.doi.org/10.1107/S1600536813018801
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author Kaupang, Åsmund
Görbitz, Carl Henrik
Bonge-Hansen, Tore
author_facet Kaupang, Åsmund
Görbitz, Carl Henrik
Bonge-Hansen, Tore
author_sort Kaupang, Åsmund
collection PubMed
description The asymmetric unit of the title compound, C(8)H(10)N(6)O(2), contains one-half mol­ecule, which is completed by a crystallographic center of symmetry. The piperazine ring adopts a chair conformation. In the crystal, weak C—H⋯O inter­actions link the mol­ecules into layers parallel to the bc plane. The crystal packing also exhibits short N⋯N contacts of 3.0467 (16) Å between the terminal diazo N atoms from neighbouring mol­ecules.
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spelling pubmed-37937442013-10-09 1,4-Bis(2-diazo­acet­yl)piperazine Kaupang, Åsmund Görbitz, Carl Henrik Bonge-Hansen, Tore Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(8)H(10)N(6)O(2), contains one-half mol­ecule, which is completed by a crystallographic center of symmetry. The piperazine ring adopts a chair conformation. In the crystal, weak C—H⋯O inter­actions link the mol­ecules into layers parallel to the bc plane. The crystal packing also exhibits short N⋯N contacts of 3.0467 (16) Å between the terminal diazo N atoms from neighbouring mol­ecules. International Union of Crystallography 2013-07-13 /pmc/articles/PMC3793744/ /pubmed/24109331 http://dx.doi.org/10.1107/S1600536813018801 Text en © Kaupang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kaupang, Åsmund
Görbitz, Carl Henrik
Bonge-Hansen, Tore
1,4-Bis(2-diazo­acet­yl)piperazine
title 1,4-Bis(2-diazo­acet­yl)piperazine
title_full 1,4-Bis(2-diazo­acet­yl)piperazine
title_fullStr 1,4-Bis(2-diazo­acet­yl)piperazine
title_full_unstemmed 1,4-Bis(2-diazo­acet­yl)piperazine
title_short 1,4-Bis(2-diazo­acet­yl)piperazine
title_sort 1,4-bis(2-diazo­acet­yl)piperazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793744/
https://www.ncbi.nlm.nih.gov/pubmed/24109331
http://dx.doi.org/10.1107/S1600536813018801
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AT bongehansentore 14bis2diazoacetylpiperazine

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