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2-Bromo-5-fluorobenzaldehyde
In the title compound, C(7)H(4)BrFO, the benzaldehyde O atom is found to be trans to the 2-bromo substituent. In the crystal, short Br⋯F interactions between the bromine and fluorine substituents are observed at distances of 3.1878 (14), 3.3641 (13) and 3.3675 (14) Å. Offset face-to-face π-stacking...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793748/ https://www.ncbi.nlm.nih.gov/pubmed/24109335 http://dx.doi.org/10.1107/S1600536813018783 |
| _version_ | 1782287107311534080 |
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| author | Tureski, Robert E. Tanski, Joseph M. |
| author_facet | Tureski, Robert E. Tanski, Joseph M. |
| author_sort | Tureski, Robert E. |
| collection | PubMed |
| description | In the title compound, C(7)H(4)BrFO, the benzaldehyde O atom is found to be trans to the 2-bromo substituent. In the crystal, short Br⋯F interactions between the bromine and fluorine substituents are observed at distances of 3.1878 (14), 3.3641 (13) and 3.3675 (14) Å. Offset face-to-face π-stacking interactions are also observed for both of the independent molecules in the asymmetric unit running parallel to the crystallographic b axis, characterized by centroid–centroid distances of 3.8699 (2) and 3.8699 (2) Å. |
| format | Online Article Text |
| id | pubmed-3793748 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-37937482013-10-09 2-Bromo-5-fluorobenzaldehyde Tureski, Robert E. Tanski, Joseph M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(7)H(4)BrFO, the benzaldehyde O atom is found to be trans to the 2-bromo substituent. In the crystal, short Br⋯F interactions between the bromine and fluorine substituents are observed at distances of 3.1878 (14), 3.3641 (13) and 3.3675 (14) Å. Offset face-to-face π-stacking interactions are also observed for both of the independent molecules in the asymmetric unit running parallel to the crystallographic b axis, characterized by centroid–centroid distances of 3.8699 (2) and 3.8699 (2) Å. International Union of Crystallography 2013-07-13 /pmc/articles/PMC3793748/ /pubmed/24109335 http://dx.doi.org/10.1107/S1600536813018783 Text en © Tureski and Tanski 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Tureski, Robert E. Tanski, Joseph M. 2-Bromo-5-fluorobenzaldehyde |
| title | 2-Bromo-5-fluorobenzaldehyde |
| title_full | 2-Bromo-5-fluorobenzaldehyde |
| title_fullStr | 2-Bromo-5-fluorobenzaldehyde |
| title_full_unstemmed | 2-Bromo-5-fluorobenzaldehyde |
| title_short | 2-Bromo-5-fluorobenzaldehyde |
| title_sort | 2-bromo-5-fluorobenzaldehyde |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793748/ https://www.ncbi.nlm.nih.gov/pubmed/24109335 http://dx.doi.org/10.1107/S1600536813018783 |
| work_keys_str_mv | AT tureskiroberte 2bromo5fluorobenzaldehyde AT tanskijosephm 2bromo5fluorobenzaldehyde |