(Di­methyl­phosphor­yl)methanaminium iodide–(di­methyl­phosphor­yl)methan­amine (1/1)

The asymmetric unit of the title structure, C(3)H(11)NOP(+)·I(−)·C(3)H(10)NOP, consists of one (di­methyl­phosphor­yl)methanamine (dpma) mol­ecule, one (di­methyl­phosphor­yl)methanaminium (dpmaH) ion and one iodide counter-anion. In the crystal, medium–strong to weak N—H⋯O and N—H⋯N hydrogen bonds...

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Detalles Bibliográficos
Autor principal: Reiss, Guido J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793753/
https://www.ncbi.nlm.nih.gov/pubmed/24109340
http://dx.doi.org/10.1107/S1600536813019004
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author Reiss, Guido J.
author_facet Reiss, Guido J.
author_sort Reiss, Guido J.
collection PubMed
description The asymmetric unit of the title structure, C(3)H(11)NOP(+)·I(−)·C(3)H(10)NOP, consists of one (di­methyl­phosphor­yl)methanamine (dpma) mol­ecule, one (di­methyl­phosphor­yl)methanaminium (dpmaH) ion and one iodide counter-anion. In the crystal, medium–strong to weak N—H⋯O and N—H⋯N hydrogen bonds connect dpmaH cations and dpma mol­ecules into strands along [001]. The iodide counter-anions form only very weak hydrogen bonds. The crystal used for the diffraction study was found to be an inversion twin with a ratio of 0.83 (2):0.17 (2). The title structure is isotypic to that of dpmaH[ClO(4)]·dpma [Buhl et al. (2013 ▶). Crystals 3, 350–362].
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spelling pubmed-37937532013-10-09 (Di­methyl­phosphor­yl)methanaminium iodide–(di­methyl­phosphor­yl)methan­amine (1/1) Reiss, Guido J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title structure, C(3)H(11)NOP(+)·I(−)·C(3)H(10)NOP, consists of one (di­methyl­phosphor­yl)methanamine (dpma) mol­ecule, one (di­methyl­phosphor­yl)methanaminium (dpmaH) ion and one iodide counter-anion. In the crystal, medium–strong to weak N—H⋯O and N—H⋯N hydrogen bonds connect dpmaH cations and dpma mol­ecules into strands along [001]. The iodide counter-anions form only very weak hydrogen bonds. The crystal used for the diffraction study was found to be an inversion twin with a ratio of 0.83 (2):0.17 (2). The title structure is isotypic to that of dpmaH[ClO(4)]·dpma [Buhl et al. (2013 ▶). Crystals 3, 350–362]. International Union of Crystallography 2013-07-13 /pmc/articles/PMC3793753/ /pubmed/24109340 http://dx.doi.org/10.1107/S1600536813019004 Text en © Guido J. Reiss 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Reiss, Guido J.
(Di­methyl­phosphor­yl)methanaminium iodide–(di­methyl­phosphor­yl)methan­amine (1/1)
title (Di­methyl­phosphor­yl)methanaminium iodide–(di­methyl­phosphor­yl)methan­amine (1/1)
title_full (Di­methyl­phosphor­yl)methanaminium iodide–(di­methyl­phosphor­yl)methan­amine (1/1)
title_fullStr (Di­methyl­phosphor­yl)methanaminium iodide–(di­methyl­phosphor­yl)methan­amine (1/1)
title_full_unstemmed (Di­methyl­phosphor­yl)methanaminium iodide–(di­methyl­phosphor­yl)methan­amine (1/1)
title_short (Di­methyl­phosphor­yl)methanaminium iodide–(di­methyl­phosphor­yl)methan­amine (1/1)
title_sort (di­methyl­phosphor­yl)methanaminium iodide–(di­methyl­phosphor­yl)methan­amine (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793753/
https://www.ncbi.nlm.nih.gov/pubmed/24109340
http://dx.doi.org/10.1107/S1600536813019004
work_keys_str_mv AT reissguidoj dimethylphosphorylmethanaminiumiodidedimethylphosphorylmethanamine11

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